901742

Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride

≥95%

• Sinónimos: (^PyrN^MeNN)Ni-Cl, (SP-4-4)-Chloro[N₁,N₁-dimethyl-N₂-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN₁,κN₂]nickel, Second-generation Nickamine
• Fórmula empírica (notación de Hill): C₁₈H₂₂ClN₃Ni
• Peso molecular: 374.53
• UNSPSC Code: 12352101

Propiedades

• assay: ≥95%
• form: powder or crystals
• reaction suitability: core: nickel; reagent type: catalyst
• SMILES string: CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl

Descripción

Application

As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.

Other Notes

From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Información de seguridad

• Storage Class: 13 - Non Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable