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15338

Sigma-Aldrich

Lead(II) oxide

puriss. p.a., ≥99.0% (KT), yellow

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About This Item

Linear Formula:
PbO
CAS Number:
Molecular Weight:
223.20
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥99.0% (KT)
form:
powder

vapor pressure

10 mmHg ( 0 °C)

Quality Level

grade

puriss. p.a.

Assay

≥99.0% (KT)

form

powder

impurities

≤0.001% total nitrogen (N)

color

yellow

pH

9.9 (20 °C, 100 g/L)

mp

886 °C (lit.)

anion traces

chloride (Cl-): ≤20 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤10 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES string

O=[PbH2]

InChI

1S/O.Pb

InChI key

YEXPOXQUZXUXJW-UHFFFAOYSA-N

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General description

Lead(II) oxide exists in two forms: red, tetragonal PbO and yellow rhombic PbO. It is amphoteric in nature but basic character is more prominent. It reacts with water and carbon dioxide to form basic lead(II) carbonate. Industrial preparation of PbO is by oxidation of molten lead with O2 or thermal decomposition of lead(II) nitrate, carbonate or hydroxide.1
Lead(II) oxide is a crystalline solid, which can be prepared by decomposition of lead carbonate or by heating molten lead in the presence of air. It can be used in the synthesis of lead(II) ethanoate by reaction with ethanoic acid.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Lact. - Repr. 1A - STOT RE 1

Target Organs

Central nervous system,Kidney,Blood

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Dhingra A
The Sterling Dictionary Of Chemistry (1999)
Gerrans.C.G, et al
Sasol Encyclopaedia of Science and Technology (2004)
Synthesis of 3-O-methylgallic acid a powerful antioxidant by electrochemical conversion of syringic acid.
Gargouri OD, Gargouri B, Trabelsi SK, et al.
Biochimica et Biophysica Acta, 1830(6), 3643-3649 (2013)
E M Ibragimova et al.
Journal of nanoscience and nanotechnology, 12(11), 8818-8821 (2013-02-21)
Widely used SiO2-PbO glasses can be a good model for studying electron structure of insulator-metal interface with many Si-O-Pb bonds and eutectic Pb-Si mixture. Gamma-radiation of 60Co with an energy of -1.25 MeV generates efficiently electronic and hole structure defects
Deepak Kumar Mohanty et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 89, 264-267 (2012-01-24)
Triply ionized thulium/thulium--ytterbium doped/codoped TeO2-Pb3O4 (TPO) glasses have been fabricated by classical quenching method. The upconversion emission spectra in the Tm3+/Tm3+-Yb3+ doped/codoped glasses upon excitation with a diode laser lasing at ∼980 nm has been studied. Effect of the addition

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