156477
4-(Dimethylamino)benzaldehyde
ACS reagent, 99%
Synonym(s):
Ehrlich’s reagent
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About This Item
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grade
ACS reagent
Quality Level
Assay
99%
form
powder
ign. residue
≤0.1%
mp
72-75 °C (lit.)
solubility
alcohol: passes test (APHA ≤60)
hydrochloric acid: passes test
λmin
369 nm
λmax
385 nm
SMILES string
CN(C)c1ccc(C=O)cc1
InChI
1S/C9H11NO/c1-10(2)9-5-3-8(7-11)4-6-9/h3-7H,1-2H3
InChI key
BGNGWHSBYQYVRX-UHFFFAOYSA-N
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Application
4-(Dimethylamino)benzaldehyde has been used in the preparation of trans-4-dimethylamino-4′-nitrostilbene.
Forms colored condensation products (Schiff bases) with pyrroles and primary amines.
Forms colored condensation products (Schiff bases) with pyrroles and primary amines.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Sens. 1B
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
327.2 °F - closed cup
Flash Point(C)
164 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The Journal of Organic Chemistry, 59, 6038-6038 (1994)
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Journal of Luminescence, 27(4), 339-355 (1982)
Journal of fluorescence, 28(1), 13-19 (2014-08-12)
N,N-dimethyl-N'-picryl-4,4'-stilbenediamine (DMPSDA) was prepared, purified and crystallised in a form of black lustrous crystals, and its absorption and fluorescence spectra were recorded in cyclohexane, acetonitrile and dimethyl sulfoxide. Non-emissive intramolecular charge transfer state (ICT) was clearly observed in this molecule
Journal of the American Chemical Society, 116, 3760-3760 (1994)
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