Skip to Content
Merck
All Photos(3)

Documents

78429

Sigma-Aldrich

p-Phenylenediamine

≥99.0% (GC/NT)

Synonym(s):

1,4-Benzenediamine, 1,4-Diaminobenzene, 1,4-Phenylenediamine

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
C6H4(NH2)2
CAS Number:
Molecular Weight:
108.14
Beilstein:
742029
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

vapor density

3.7 (vs air)

vapor pressure

1.08 mmHg ( 100 °C)

description

anti-fade reagent

Assay

≥99.0% (GC/NT)

form

flakes

bp

267 °C (lit.)

mp

138-143 °C (lit.)

SMILES string

Nc1ccc(N)cc1

InChI

1S/C6H8N2/c7-5-1-2-6(8)4-3-5/h1-4H,7-8H2

InChI key

CBCKQZAAMUWICA-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

p-Phenylenediamine (1,4-Phenylenediamine or PPDA) can be used as a precursor for the synthesis of asymmetric bis-schiff bases , angular diazatricycles , poly (p-phenylenediamine) and aromatic polyamides.
It can also be used as a reactant in the synthesis of azo-schiff-base complexes of various metals.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Sens. 1 - STOT SE 1 Oral

Target Organs

Kidney,Heart,Musculo-skeletal system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis and characterization of VO (II), Co (II), Ni (II), Cu (II) and Zn (II) complexes of chromone based azo-linked Schiff base ligand
Anitha C, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 98(8), 35-42 (2012)
Keto-enol tautomerism in asymmetric Schiff bases derived from p-phenylenediamine
Uvzarevic K, et al.
Journal of Molecular Structure, 984(1-3), 232-239 (2010)
Studies on thermal and mechanical properties of polyimide-clay nanocomposites
Agag T, et al.
Polymer, 42(8), 3399-3408 (2001)
The synthesis of aromatic diazatricycles from phenylenediamine-bis (methylene Meldrum's acid) derivatives
Graf GI, et al.
Tetrahedron, 58(44), 9095-9100 (2002)
Facile synthesis of poly (p-phenylenediamine)/MWCNT nanocomposites and characterization for investigation of structural effects of carbon nanotubes
Pham QL, et al.
Bulletin of Materials Science, 34(1), 37-43 (2011)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service