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Three-dimensional homochiral manganese-lanthanide frameworks based on chiral camphorates with multi-coordination modes.

Chemical communications (Cambridge, England) (2013-02-12)
Dong-Bin Dang, Bing An, Yan Bai, Guang-Shui Zheng, Jing-Yang Niu
RESUMEN

A series of 3D homochiral manganese-lanthanide frameworks have been synthesized based on chiral camphoric acid. In the heterometallic features, D-camphoric acids are unprecedentedly embedded in three coordination modes.

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Sigma-Aldrich
(±)-Alcanfor, 96%
Sigma-Aldrich
(1R)-(+)-Camphor, 98%
Sigma-Aldrich
D-Camphor, ≥97%, FG
Sigma-Aldrich
(1S)-(−)-Camphor, 95%
Sigma-Aldrich
(±)-Alcanfor, ≥95.5%
Supelco
D-Camphor, Pharmaceutical Secondary Standard; Certified Reference Material
Sigma-Aldrich
(±)-Alcanfor, meets analytical specification of Ph. Eur., BP, racemic, ≥95% (GC)
Sigma-Aldrich
(±)-Alcanfor, purum, synthetic, ≥95.0% (GC)
Supelco
(−)-Camphor, analytical standard
(±)-Alcanfor, European Pharmacopoeia (EP) Reference Standard
(±)-Alcanfor, primary reference standard
Sigma-Aldrich
(±)-Alcanfor, SAJ first grade, ≥96.0%