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D19605

Sigma-Aldrich

1,8-Diamino-p-menthane, mixture of cis and trans isomers

technical grade, 85%

Synonym(s):

1,8-p-Menthanediamine

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About This Item

Empirical Formula (Hill Notation):
C10H22N2
CAS Number:
Molecular Weight:
170.30
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

vapor pressure

10 mmHg ( 20 °C)

Assay

85%

form

liquid

refractive index

n20/D 1.4805 (lit.)

bp

107-126 °C/10 mmHg (lit.)

mp

−45 °C (lit.)

density

0.914 g/mL at 25 °C (lit.)

SMILES string

CC(C)(N)C1CCC(C)(N)CC1

InChI

1S/C10H22N2/c1-9(2,11)8-4-6-10(3,12)7-5-8/h8H,4-7,11-12H2,1-3H3

InChI key

KOGSPLLRMRSADR-UHFFFAOYSA-N

Application

1,8-Diamino-p-menthane is generally used in the synthesis of various Schiff bases that are used in the preparation of coordination complexes with Cu(II), Zn(II), Cr(III), Fe(III) and Co(III) ions. It is also used as a precursor to synthesize heterocyclic Schiff base derivatives with herbicidal activity.

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Skin Corr. 1B

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

199.4 °F - closed cup

Flash Point(C)

93 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Cr (III), Fe (III) and Co (III) complexes of tetradentate (ONNO) Schiff base ligands: synthesis, characterization, properties and biological activity.
Keskio?lu E, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 70(3), 634-640 (2008)
High value-added application of turpentine as a potential renewable source for the synthesis of heterocyclic Schiff base derivatives of cis-1, 8-p-menthane-diamine serving as botanical herbicides.
Zhu S, et al.
Industrial Crops and Products, 115(3), 111-116 (2018)
Copper (II) and zinc (II) complexes of thiophene/furan carboxamides: synthesis, structure and properties.
Gunduzalp AB and Erk B
Russian Journal of Inorganic Chemistry, 55(7), 1094-1102 (2010)

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