Skip to Content
Merck
All Photos(5)

Key Documents

761001

Sigma-Aldrich

Lithium nickel manganese cobalt oxide

greener alternative

powder, <0.5 μm particle size, >98%

Synonym(s):

NMC

Sign Into View Organizational & Contract Pricing
All Photos(5)

About This Item

Linear Formula:
LiNi0.33Mn0.33Co0.33O2
CAS Number:
346417-97-8
MDL number:
MFCD00460869
UNSPSC Code:
26111700
NACRES:
NA.23
Pricing and availability is not currently available.

grade

battery grade

Quality Level

100

Assay

>98%

form

powder

mol wt

Mw 96.46 g/mol

composition

LiNi0.33Mn0.33Co0.33O2

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

particle size

<0.5 μm

mp

>290 °C (lit.)

density

2.11 g/cm3

application(s)

battery manufacturing

greener alternative category

, Enabling

General description

Lithium nickel manganese cobalt oxide (NMC) is a class of electrode material that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

NMC is a novel lithium insertion electrode material for advanced lithium-ion batteries. Mn doping significantly increases the thermal stability besides increasing the electrochemical charge-discharge behavior.
NMC111 (lithium nickel-manganese-cobalt oxide with a stoichiometry of 1:1:1) is a promising cathode material used in advanced lithium-ion batteries, particularly for electric vehicle applications, due to its high energy density and long cycle life. NMC111 powder has a layered crystal structure that enables efficient, reversible lithium-ion diffusion, which is essential for good electrochemical performance. Manganese doping improves the thermal stability of the material while enhancing its electrochemical charge-discharge behavior. Compared to other NMC materials, NMC111 has a higher thermal stability and is less prone to thermal runaway, making it a safer option for battery applications.

Features and Benefits

Our NMC111 has engineered improvements over other LiNMC materials including thermal stability and high conductivity:
  • More Reliable
  • Longer Cycle Life
  • Bulk and Pilot Scale Available

Legal Information

Product of Engi-Mat Co.

related product

Product No.
Description
Pricing

442704

Lithium cobalt(III) oxide, 99.8% trace metals basis

746711

Lithium hexafluorophosphate solution, in ethylene carbonate and dimethyl carbonate, 1.0 M LiPF6 in EC/DMC=50/50 (v/v), battery grade

746738

Lithium hexafluorophosphate solution, in ethylene carbonate and ethyl methyl carbonate, 1.0 M LiPF6 in EC/EMC=50/50 (v/v), battery grade

746746

Lithium hexafluorophosphate solution, in ethylene carbonate and diethyl carbonate, 1.0 M LiPF6 in EC/DEC=50/50 (v/v), battery grade

901685

Lithium hexafluorophosphate solution, in ethylene carbonate, dimethyl carbonate and diethyl carbonate, LiPF6 in EC/DMC/DEC=1:1:1 (v/v/v) 1.0 M, battery grade

915432

Lithium manganese nickel oxide, spinel, powder, battery grade

916439

Lithium Manganese Oxide spinel (LMO) powder, battery grade

915173

LATP-coated Lithium Manganese Nickel Oxide (LMNO), powder, battery grade

916196

Carbon coated Lithium Titanate (“LTO”) powder, battery grade

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Statements

H317,H351

Hazard Classifications

Carc. 2 - Skin Sens. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCW1642
MKCT7459
MKCS3197
MKCQ4516
MKCN9228

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Choi, J.; Manthiram, A.; J.
Journal of the Electrochemical Society, 152, A1714-A1714 (2005)
A bi-functional lithium difluoro (oxalato) borate additive for lithium cobalt oxide/lithium nickel manganese cobalt oxide cathodes and silicon/graphite anodes in lithium-ion batteries at elevated temperatures
Lee SJ, et al.
Electrochimica Acta, 137, 1-8 (2014)
Belharouak, I.; et al.
Journal of Power Sources, 123, 247-247 (2003)
Impedance change and capacity fade of lithium nickel manganese cobalt oxide-based batteries during calendar aging
Schmitt J, et al.
Journal of Power Sources, 353, 183-194 (2017)
Challenges for rechargeable Li batteries
Goodenough JB and Kim Y
Chemistry of Materials, 22(3), 587-603 (2009)
View All Related Papers

Articles

Advances in Li-Metal Fluoride Battery

Professor Qiao's review explores stable microstructures for lithium metal fluoride batteries, advancing energy storage technologies.

Advances in Li-Metal Fluoride Battery

Professor Qiao's review explores stable microstructures for lithium metal fluoride batteries, advancing energy storage technologies.

Advances in Li-Metal Fluoride Battery

Professor Qiao's review explores stable microstructures for lithium metal fluoride batteries, advancing energy storage technologies.

Advances in Li-Metal Fluoride Battery

Professor Qiao's review explores stable microstructures for lithium metal fluoride batteries, advancing energy storage technologies.

See All

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service