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722987

Sigma-Aldrich

2-Cyano-2-propyl benzodithioate

>97% (HPLC)

Synonym(s):

2-Cyanopropan-2-yl benzodithioate

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About This Item

Empirical Formula (Hill Notation):
C11H11NS2
CAS Number:
201611-85-0
Molecular Weight:
221.34
MDL number:
MFCD09037881
UNSPSC Code:
12352100
PubChem Substance ID:
329763965
NACRES:
NA.23
Pricing and availability is not currently available.

Assay

>97% (HPLC)

form

solid or liquid

refractive index

n20/D 1.621

mp

28-31 °C

density

1.146 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(SC(=S)c1ccccc1)C#N

InChI

1S/C11H11NS2/c1-11(2,8-12)14-10(13)9-6-4-3-5-7-9/h3-7H,1-2H3

InChI key

IDSLBLWCPSAZBL-UHFFFAOYSA-N

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General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylate and methacrylamide monomers. Chain Transfer Agent (CTA)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H317

Hazard Classifications

Skin Sens. 1

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

>230.0 °F - closed cup

Flash Point(C)

> 110 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6195
MKCW3898
MKCT4216
MKCT6179
MKCS7725

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Ryuichi Nakatani et al.
ACS applied materials & interfaces, 9(37), 31266-31278 (2017-03-18)
In this study, a series of perpendicular lamellae-forming poly(polyhedral oligomeric silsesquioxane methacrylate-block-2,2,2-trifluoroethyl methacrylate)s (PMAPOSS-b-PTFEMAs) was developed based on the bottom-up concept of creating a simple yet effective material by tailoring the chemical properties and molecular composition of the material. The
Laura Marcela Forero Ramirez et al.
Carbohydrate polymers, 224, 115153-115153 (2019-09-02)
A multi-reactive polysaccharide-based transurf (acting both as macro-Chain Transfer Agent and stabilizer) was used to confine RAFT polymerization of methyl methacrylate (MMA) at the oil/water (o/w) miniemulsion interface. Dithiobenzoate groups and hydrophobic aliphatic side chains were introduced onto dextran, conferring
Izumi Fukumoto et al.
PloS one, 8(11), e82540-e82540 (2013-12-07)
The immunostimulatory effects of the representative dental resin monomer 2-hydroxyethyl methacrylate (HEMA), a HEMA derivative that does not contain a double bond (2-hydroxyethyl isobutyrate, HEIB), and polymerized water-soluble oligomers of HEMA (PHEMA) were investigated. It is known that expression levels
Laure Gevaux et al.
Polymers, 11(2) (2019-04-10)
Fouling Release Coatings are marine antifouling coatings based on silicone elastomers. Contrary to commonly used biocide-based antifouling coatings, they do not release biocides into the marine environment, however, they suffer from poor antifouling efficacy during idle periods. To improve their
Sungyoup Hong et al.
PloS one, 12(1), e0169262-e0169262 (2017-01-07)
In this report, we demonstrate the pH-dependent, in vitro antimicrobial activity of a cationic, amphiphilic random copolymer against clinical isolates of drug-resistant Staphylococcus aureus. The polymer was developed toward a long-term goal of potential utility in the treatment of skin
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Articles

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

See All

Protocols

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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