Skip to Content
Merck
All Photos(1)

Documents

429112

Sigma-Aldrich

2-Bromo-6-methylpyridine

98%

Synonym(s):

2-Bromo-6-picoline, 2-Methyl-6-bromopyridine, 6-Bromo-2-methylpyridine, 6-Bromo-2-picoline, 6-Methyl-2-bromopyridine

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C6H6BrN
CAS Number:
5315-25-3
Molecular Weight:
172.02
EC Number:
226-173-4
MDL number:
MFCD00040743
UNSPSC Code:
12352100
PubChem Substance ID:
24866838
NACRES:
NA.22

Assay

98%

form

liquid

refractive index

n20/D 1.562 (lit.)

bp

102-103 °C/20 mmHg (lit.)

density

1.512 g/mL at 25 °C (lit.)

SMILES string

Cc1cccc(Br)n1

InChI

1S/C6H6BrN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3

InChI key

SOHDPICLICFSOP-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

2-Bromo-6-methylpyridine is a bromopyridine derivative. It is formed when 2-chloro-6-methylpyridine is heated with bromotrimethylsilane. Its synthesis from various methods have been reported.

Application

2-Bromo-6-methylpyridine may be used in the synthesis of the following:
  • 6,6′-dimethyl-2,2′-bipyridine
  • 6-methyl-2-pyridyl-2-pyridylmethanone
  • 2-methyl-6-(trimethylsilyl)-pyridine
  • N,N′-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy)
  • 2-methyl-6-(trimethylstannanyl)pyridine
  • 2-(6-methylpyridin-2-yl)propan-2-ol
  • bis[(2-bromo-6-methylpyridinium)hexafluorosilicate] monohydrate

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

206.6 °F - closed cup

Flash Point(C)

97 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Nickel complexes with new bidentate P,N phosphinitooxazoline and-pyridine ligands: Application for the catalytic oligomerization of ethylene.
Speiser F, et al.
Inorganic Chemistry, 43(5), 1649-1658 (2004)
Block copolymers with bipyridine containing segments: Synthesis and self-organization by Cu (I) complexation.
2Eisenbach CD, et al.
Macromolecular Chemistry and Physics, 196(4), 1077-1091 (1995)
Catalytic Asymmetric Synthesis of Bis-armed Aromatic Amino Acid Derivatives. Problems Related to the Synthesis of Enantiomerically Pure Bis-methyl Ester of the (S,S)-Pyridine-2,6-diyl Bis-alanine.
Basu B and FrejdT T.
Acta Chemica Scandinavica, 50, 316-322 (1996)
Preparation, structure and properties of pyridinium/bipyridinium hexafluorosilicates.
Gelmboldt VO, et al.
Journal of Fluorine Chemistry, 160, 57-63 (2014)
Crystallographic report:[N,N'-Bis-(6-methylpyrid-2-ylium)-(1R, 2R)-1,2-diaminocyclohexane] bis-[(p-cymene)-trichlororuthenate(II)].
Cabeza JA, et al.
Applied Organometallic Chemistry, 19(1), 209-210 (2005)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service