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368598

Sigma-Aldrich

4,4′-Bis(2-benzoxazolyl)stilbene

97%

Synonym(s):

1,2-Bis(4-(benzo[d]oxazol-2-yl)phenyl)ethene, 2,2′-(1,2-Ethenediyl)bis(4,1-phenylene)bisbenzoxazole, 2,2′-(1,2-Ethenediyldi-4,1-phenylene)bis[benzoxazole], 2,2′-(Vinylenedi-p-phenylene)bisbenzoxazole, 2-[4-[2-[4-(1,3-Benzoxazol-2-yl)phenyl]ethenyl]phenyl]-1,3-benzoxazole, 4,4′-Di(benzoxazol-2-yl)stilbene, p,p′-Bis(2-benzoxazolyl)stilbene

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About This Item

Empirical Formula (Hill Notation):
C28H18N2O2
CAS Number:
1533-45-5
Molecular Weight:
414.45
EC Number:
216-245-3
MDL number:
MFCD00022846
UNSPSC Code:
12352100
PubChem Substance ID:
24862920
NACRES:
NA.22

Assay

97%

form

powder

mp

>300 °C (lit.)

λmax

372 nm

SMILES string

c1ccc2oc(nc2c1)-c3ccc(\C=C\c4ccc(cc4)-c5nc6ccccc6o5)cc3

InChI

1S/C28H18N2O2/c1-3-7-25-23(5-1)29-27(31-25)21-15-11-19(12-16-21)9-10-20-13-17-22(18-14-20)28-30-24-6-2-4-8-26(24)32-28/h1-18H/b10-9+

InChI key

ORACIQIJMCYPHQ-MDZDMXLPSA-N

Related Categories

General description

4,4′-Bis(2-benzoxazolyl)stilbene (BBS) is reported to exhibit consistently high absolute fluorescence quantum yields and a monoexponential lifetime in solutions. The photophysics of BBS dispersed in poly(propylene) (PP) films has been investigated. BBS is reported as a food-grade dye. BBS is also reported as excimer-forming, photoluminescent chromophore.

Application

4,4′-Bis(2-benzoxazolyl)stilbene (BBS) is suitable for use in the preparation of poly(propylene) (PP) films containing different concentrations of BBS. BBS may be employed as a viscosity-sensitive fluorophore to investigate the curing parameters in fabrication of UV-cured automotive organic protective coatings. BBS may be used in the preparation of polymeric film sensors based on excimer luminescence and responsive to both mechanical and temperature stress, by its dispersion into a thermoplastic aliphatic biodegradable polyester [poly(1,4-butylene succinate).
Optical brightener for plastics

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Luminescent bis (benzoxazolyl) stilbene as a molecular probe for poly (propylene) film deformation.
Pucci A, et al.
Macromolecular Rapid Communications, 26(13), 1043-1048 (2005)
Radislav A Potyrailo et al.
Analytical chemistry, 74(21), 5676-5680 (2002-11-16)
An automated analytical system has been implemented for the high-throughput optimization of processing conditions such as curing parameters in fabrication of UV-cured automotive organic protective coatings. Selection of optimum process conditions of combinatorial arrays of coatings is essential to correlate
M Amine Fourati et al.
The journal of physical chemistry. A, 117(5), 836-844 (2013-01-12)
In solution, 4,4'-bis(2-benzoxazolyl)stilbene (BBS) was found to exhibit consistently high absolute fluorescence quantum yields (Φ(fl) ≥ 0.88) and a monoexponential lifetime, both independent of BBS concentration. The BBS steady-state and time-resolved photophysics were investigated by different techniques to understand the
Bis (benzoxazolyl) stilbene excimers as temperature and deformation sensors for biodegradable poly (1, 4-butylene succinate) films.
Cuia FD.
Journal of Materials Chemistry, 17(8), 1043-1048 (2005)
Yuluan Wu et al.
Food chemistry, 243, 162-167 (2017-11-18)
A sensitive UPLC-MS/MS method was established for the simultaneous determination of seven fluorescent whitening agents in flour matrix. Samples were ultrasonically extracted by trichloromethane-acetone. Then analytes were separated on a C18 column and detected by MS/MS. The developed method was
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