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126306

Sigma-Aldrich

1,3-Dimethoxybenzene

≥98%

Synonym(s):

Dimethylresorcinol, Resorcinol dimethyl ether

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About This Item

Linear Formula:
C6H4(OCH3)2
CAS Number:
151-10-0
Molecular Weight:
138.16
Beilstein:
878582
EC Number:
205-783-4
MDL number:
MFCD00008384
UNSPSC Code:
12352100
PubChem Substance ID:
24847714
NACRES:
NA.22

Assay

≥98%

form

liquid

refractive index

n20/D 1.524 (lit.)

bp

85-87 °C/7 mmHg (lit.)

density

1.055 g/mL at 25 °C (lit.)

SMILES string

COc1cccc(OC)c1

InChI

1S/C8H10O2/c1-9-7-4-3-5-8(6-7)10-2/h3-6H,1-2H3

InChI key

DPZNOMCNRMUKPS-UHFFFAOYSA-N

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Application

1,3-Dimethoxybenzene has been used in the synthesis of novel oxathiane spiroketal donors. It forms pi- and O-ylidic complexes with dichlorocarbene (CCl(2)).

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

190.4 °F - closed cup

Flash Point(C)

88 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Helena Zahradnícková et al.
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Bioscience, biotechnology, and biochemistry, 73(11), 2547-2548 (2009-11-10)
An efficient synthesis of tri-O-methylated resveratrol is presented using an advanced Heck reaction promoted by Pd(dba)(2) in the presence of P(t-Bu)(3).
Martin A Fascione et al.
Carbohydrate research, 348, 6-13 (2011-12-28)
Novel oxathiane spiroketal donors have been synthesised and activated via an umpolung S-arylation strategy using 1,3,5-trimethoxybenzene and 1,3-dimethoxybenzene. The comparative reactivity of the resulting 2,4,6-trimethoxyphenyl (TMP)- and 2,4-dimethoxyphenyl (DMP)-oxathiane spiroketal sulfonium ions is discussed, and their α-stereoselectivity in glycosylation reactions
Shih Chang Yang et al.
The journal of physical chemistry. A, 114(42), 11144-11152 (2010-08-14)
We applied two-color resonant two-photon mass-analyzed threshold ionization (MATI) spectroscopy to investigate the molecular properties of the selected rotamers of o-dimethoxybenzene (ODMB) and m-dimethoxybenzene (MDMB). The present experimental results show that only one stable configuration is involved in the photoexcitation
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