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101915

Sigma-Aldrich

2,4-Diaminotoluene

98%

Synonym(s):

4-Methyl-m-phenylenediamine, 2,4-Diaminotoluene, 2,4-Toluenediamine, 4-Methyl-1,3-phenylenediamine

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About This Item

Linear Formula:
CH3C6H3(NH2)2
CAS Number:
95-80-7
Molecular Weight:
122.17
Beilstein:
2205839
EC Number:
202-453-1
MDL number:
MFCD00007804
UNSPSC Code:
12162002
PubChem Substance ID:
24846558
NACRES:
NA.23

Quality Level

200

Assay

98%

form

solid

bp

283-285 °C (lit.)

mp

97-99 °C (lit.)

SMILES string

Cc1ccc(N)cc1N

InChI

1S/C7H10N2/c1-5-2-3-6(8)4-7(5)9/h2-4H,8-9H2,1H3

InChI key

VOZKAJLKRJDJLL-UHFFFAOYSA-N

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Application

  • Employing UV/H2O2 process for degradation of 2, 4-Diaminotoluene in synthetic wastewater: This study explores the degradation of carcinogenic Toluene-2, 4-diamine in synthetic wastewater using the UV/H2O2 process, highlighting its potential for improving water treatment methods (J Hosseini, A Shokri, 2017).
  • Development of magnetic, ferrite supported palladium catalysts for 2, 4-dinitrotoluene hydrogenation: The paper discusses the use of Pd/NiFe2O4 catalyst for efficient hydrogenation of 2,4-dinitrotoluene to 2,4-diaminotoluene, demonstrating a high yield and potential for industrial applications (V Hajdu, M Varga, G Muránszky, G Karacs, 2021).
  • Synthesis, characterisation and energetic performance of insensitive energetic salts formed between picric acid and 2, 3-diaminotoluene, 2, 4-diaminotoluene: This paper presents the synthesis and characterization of new energetic materials, which could be significant for the development of safer explosives and pyrotechnic devices (N Şen, H Nazir, N Atҫeken, KS Hope, N Acar, 2020).

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Muta. 2 - Repr. 2 - Skin Sens. 1 - STOT RE 2

Target Organs

Liver,Kidney

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

320.0 °F - closed cup

Flash Point(C)

160 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM0486
BCCM3457
BCCM0111
BCCM0244
BCCL1721

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Jeroen A J Vanoirbeek et al.
Toxicological sciences : an official journal of the Society of Toxicology, 109(2), 256-264 (2009-04-01)
Toluene diamine (TDA) is formed when toluene diisocyanate (TDI), a potent sensitizer, comes in contact with an aqueous environment. The sensitizing capacity of TDA and the cross-reactivity between TDI and TDA are unknown. TDA (5-25%) and TDI (0.3%), dissolved in
Pei-Shan Liu et al.
Toxicology, 219(1-3), 167-174 (2005-12-13)
Toluene diisocyanate (TDI) is widely used as a chemical intermediate in the production of polyurethane. TDI-induced asthma is related to its disturbance of acetylcholine activity in most affected workers, but the relevant mechanisms are unclear. Toluene diamine (TDA) is the
Isabelle Séverin et al.
Toxicology, 213(1-2), 138-146 (2005-07-06)
2,4-Diaminotoluene (2,4-DAT) is a widely used industrial intermediate and human exposure is possible in the dye and plastics industries. We investigated the genotoxicity of the environmental pollutant, 2,4-DAT, in human HepG2 cells using the unscheduled DNA synthesis (UDS) test, the
Kazunori Narumi et al.
Mutation research, 747(2), 234-239 (2012-06-09)
Various liver micronucleus assay methods, such as those involving partial hepatectomy, treatment with mitogens, and the use of juvenile animals, have been developed. These assays have been proven to be of high sensitivity and specificity to predict hepatocarcinogenicity of compounds
Astrid Rohrbeck et al.
Toxicological sciences : an official journal of the Society of Toxicology, 118(1), 31-41 (2010-08-18)
Information on the carcinogenic potential of chemicals is primarily available for High Production Volume (HPV) products. Because of the limited knowledge gain from routine cancer bioassays and the fact that HPV chemicals are tested only, there is the need for
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