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B52808

Sigma-Aldrich

1,2-Di(4-pyridyl)ethylene

97%

Synonyme(s) :

1,2-Bis(4-pyridyl)ethylene, 4,4′-Vinylenedipyridine

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About This Item

Formule empirique (notation de Hill):
C12H10N2
Numéro CAS:
13362-78-2
Poids moléculaire :
182.22
Beilstein:
3865
Numéro CE :
236-432-3
Numéro MDL:
MFCD00006448
Code UNSPSC :
12352100
ID de substance PubChem :
24891831
Nomenclature NACRES :
NA.22
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Niveau de qualité

100

Essai

97%

Forme

crystals

Pf

148-152 °C (lit.)

Chaîne SMILES 

c1cc(ccn1)\C=C\c2ccncc2

InChI

1S/C12H10N2/c1(11-3-7-13-8-4-11)2-12-5-9-14-10-6-12/h1-10H/b2-1+

Clé InChI

MGFJDEHFNMWYBD-OWOJBTEDSA-N

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Catégories apparentées

Application

1,2-Di(4-pyridyl)ethylene is extensively used as a ligand/linker in the synthesis of a variety of metal-organic frameworks(MOFs)[1][2] and coordination polymers (CPs).[3] It is employed in the synthesis of:
  • Expanding and shrinking cadmium-based pillared layer coordination polymers showing selective guest adsorption.[4]
  • Dinuclear zinc complex that exhibits photocontrolled fluorescence.[5]
  • Platinum-based 3-D tetragonal prisms via multicomponent coordination-driven self-assembly.[6]

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315,H319,H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
STBH8635
STBJ2735
STBJ1739
STBH7356
STBH6015

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination Polymers Showing Selective Guest Adsorption.
Maji TK, et al.
Angewandte Chemie (International Edition in English), 43(25), 3269-3272 (2004)
Zhiwei Chen et al.
Dalton transactions (Cambridge, England : 2003), 47(17), 6240-6249 (2018-04-25)
Three new luminescent transition coordination polymers, namely, {[Cd(L)(4,4-bpy)]·DMF·H2O}n (1), {[Cd2(L)2(bpe)2]·3DMF·2.5H2O}n (2), and {[Cd(L)(bibp)]·2DMF}n (3), (H2L = 4,4'-[benzene-1,3-diylbis(methanediylsulfanediyl)]dibenzoic acid, 4,4-bpy = 4,4-bipyridine, bpe = 1,2-bis(4-pyridyl)ethylene, and bibp = 4,4'-bis(benzoimidazo-1-ly)biphenyl), were solvothermally synthesized using Cd2+ ions and S-containing dicarboxylate acid in the
Isoreticular Homochiral Porous Metal- Organic Structures with Tunable Pore Sizes.
Dybtsev DN, et al.
Inorganic Chemistry, 46(17), 6843-6845 (2007)
Hydrogen adsorption in an interpenetrated dynamic metal- organic framework.
Chen B, et al.
Inorganic Chemistry, 45(15), 5718-5720 (2006)
Metallosupramolecular tetragonal prisms via multicomponent coordination-driven template-free self-assembly.
Wang M, et al.
Journal of the American Chemical Society, 132(18), 6282-6283 (2010)
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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