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931578

Sigma-Aldrich

Ruthenium(III) chloride hydrate

≥99.9% trace metals basis

Synonyme(s) :

Ruthenium trichloride, Trichlororuthenium hydrate

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About This Item

Formule linéaire :
RuCl3 · xH2O
Numéro CAS:
Poids moléculaire :
207.43 (anhydrous basis)
Numéro MDL:
Code UNSPSC :
12352302
Nomenclature NACRES :
NA.21

Niveau de qualité

Pureté

≥99.9% trace metals basis

Forme

powder

Impuretés

≤1000.0 ppm (trace metals analysis)

Solubilité

acetone: soluble ((lit.))
ethanol: soluble
water: soluble

Densité

3.11 g/cm3

Chaîne SMILES 

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

Clé InChI

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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Description générale

Ruthenium chloride hydrate is a dark brown or black solid often used as a powder. The hydrate is hygroscopic and is soluble in water, ethanol, acetone, and a wide range of polar organic solvents. The anhydrous form is insoluble.
Industrially, ruthenium trichloride hydrate is produced by dissolving ruthenium oxides in hydrochloric acid. The hydrated salt is obtained by recrystallization.

Application

Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. Our RuCl3·H2O with 99.9% trace metals purity is well-suited for applications in materials science. One common application of ruthenium trichloride hydrate is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions. Researchers have used our ruthenium chloride hydrate to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles.
Another common application of ruthenium chloride hydrate is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride hydrate for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
For use in all these applications, also consider our higher-purity ruthenium chloride hydrate, 463779, with trace metals purity greater than 99.98%, which offers the best reproducibility and purity.

Pictogrammes

CorrosionExclamation markEnvironment

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution
Ramalingam, V., et al.
Advanced Materials, 31, e1903841-e1903841 (2019)
Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
Lee, Y., Suntivich, J., et al.
The Journal of Physical Chemistry Letters, 3, 399?404-399?404 (2012)
Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction
Tao, H., Choi, C., et al.
Chem, 5, 204-214 (2019)
Vinoth Ramalingam et al.
Advanced materials (Deerfield Beach, Fla.), 31(48), e1903841-e1903841 (2019-10-18)
A titanium carbide (Ti3 C2 Tx ) MXene is employed as an efficient solid support to host a nitrogen (N) and sulfur (S) coordinated ruthenium single atom (RuSA ) catalyst, which displays superior activity toward the hydrogen evolution reaction (HER).
Youngmin Lee et al.
The journal of physical chemistry letters, 3(3), 399-404 (2012-02-02)
The activities of the oxygen evolution reaction (OER) on iridium-oxide- and ruthenium-oxide-based catalysts are among the highest known to date. However, the OER activities of thermodynamically stable rutile iridium oxide (r-IrO2) and rutile iridium oxide (r-RuO2), normalized to catalyst mass

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