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771147

Sigma-Aldrich

1-Trifluoromethyl-1,2-benziodoxol-3-(1H)-one

60 wt. %, contains 40 wt. % Celatom® FW-80 as additive

Synonyme(s) :

Togni Reagent II

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About This Item

Numéro MDL:
Code UNSPSC :
12352005
ID de substance PubChem :
Nomenclature NACRES :
NA.22
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Forme

solid

Niveau de qualité

Contient

40 wt. % Celatom® FW-80 as additive

Capacité de réaction

reaction type: C-C Bond Formation

Concentration

60 wt. %

Pf

150-158 °C

Groupe fonctionnel

fluoro
iodo

Température de stockage

2-8°C

Chaîne SMILES 

FC(F)(F)[I]1OC(=O)c2ccccc12

InChI

1S/C8H4F3IO2/c9-8(10,11)12-6-4-2-1-3-5(6)7(13)14-12/h1-4H

Clé InChI

XHEOXSQMBWJOKP-UHFFFAOYSA-N

Application

Electrophilic trifluoromethylating reagent has shown to be one of the more robust trifluoromethylation reagents on the market. However, a recent report has showed this product to have potential dangerous self-reactivity neat.[1] We now offer a less self-reactive material mixed down in Celatom®, a silica-based adsorbent, which significantly reduces self-reactivity allowing for safer shipping and storage.

Informations légales

Celatom is a registered trademark of EP Minerals, LLC

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

Pictogrammes

Health hazardExclamation mark

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

Organes cibles

Lungs, Respiratory system

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Certificats d'analyse (COA)

Lot/Batch Number

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Les clients ont également consulté

Fiederling, N.;
Organic Process Research & Development, 17, 318-319 (2013)

Articles

Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.

Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.

Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.

Fluoroalkylation toolbox expands with various reagents for late-stage fluoroalkylation in organic synthesis and medicinal chemistry.

Contenu apparenté

Togni group develops ligands and reagents for constructing molecules in efficient or unprecedented ways.

Togni group develops ligands and reagents for constructing molecules in efficient or unprecedented ways.

Togni group develops ligands and reagents for constructing molecules in efficient or unprecedented ways.

Togni group develops ligands and reagents for constructing molecules in efficient or unprecedented ways.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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