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372439

Sigma-Aldrich

Perfluoro(methyldecalin), mixture of isomers

technical grade, 80%

Synonyme(s) :

Heptadecafluorodecahydro(trifluoromethyl)naphthalene

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About This Item

Formule empirique (notation de Hill):
C11F20
Numéro CAS:
51294-16-7
Poids moléculaire :
512.09
Code UNSPSC :
12352100
ID de substance PubChem :
24863035
Nomenclature NACRES :
NA.22

Qualité

technical grade

Niveau de qualité

100

Pureté

80%

Forme

liquid

Indice de réfraction

n20/D 1.317 (lit.)

Point d'ébullition

137-160 °C (lit.)

Pf

−40 °C (lit.)

Densité

1.95 g/mL at 25 °C (lit.)

Chaîne SMILES 

FC(F)(F)C1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F.FC(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C4(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C34F

InChI

1S/C11F20/c12-1-2(13,6(19,20)10(27,28)9(25,26)4(1,15)16)5(17,18)8(23,24)7(21,22)3(1,14)11(29,30)31

Clé InChI

LWRNQOBXRHWPGE-UHFFFAOYSA-N

Description générale

Perfluoro(methyldecalin) is a fluorinated solvent.

Application

Perfluoro(methyldecalin is suitable reagent used to investigate the reactions of iodide anions and anions derived from glow discharge ionization of perfluoro(methyldecalin) with positive ions derived from poly(ethylene glycol). It is suitable reagent used for the oxidation of alcohols with the ruthenium porphyrin at higher temperatures (140ºC) and elevated oxygen pressures (50psi). Perfluoro(methyldecalin (Perfluoro-1-Methyldecalin) may be used in the preparation of undecafluoro-6-trifluoromethyltetralin via defluorination.

Autres remarques

Contains perfluorodecalin

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

235.0 °F - closed cup

Point d'éclair (°C)

112.80 °C - closed cup

Équipement de protection individuelle

Eyeshields, Gloves

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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M K Bakulin et al.
Mikrobiologiia, 75(3), 371-376 (2006-07-29)
The isolates of pseudomonads (56) and of Plesiomonas shigelloides (7) exhibiting ice-forming activity were isolated from plant leaves and rhizosphere. The theoretical possibility of the application of perfluorocarbons (PFC) with a gas-transporting function (perfluorodecalin, carbogal, and perfluoromethyldecalin) for the cultivation
Vasily N Korotchenko et al.
Organic & biomolecular chemistry, 6(11), 1961-1965 (2008-05-16)
Carbonylruthenium tetrakis(pentafluorophenyl)porphyrin Ru(TPFPP)(CO) was utilized for the aerobic oxidation of alcohols. The in situ activation of the catalyst with mCPBA provided a species capable of catalyzing the oxidation of alcohols with molecular oxygen. The choice of solvent and additive was
Perfluoro-1-methyldecalin as a potential oxygen carrier with fluid scleral lenses.
M F Refojo et al.
Current eye research, 4(6), 732-733 (1985-06-01)
M K Bakulin et al.
Prikladnaia biokhimiia i mikrobiologiia, 43(4), 443-449 (2007-10-13)
The addition of perfluorocarbons (perfluorodecalin, carbogal, and perfluoromethyldecalin) to nitrogen-free liquid media during the submerged cultivation of bacteria of the genus Azotobacter was followed by (1) increases in biomass accumulation and nitrogenase activity and (2) fixation of molecular nitrogen. Addition
37. Polycyclic fluoroaromatic compounds. Part II. Perfluoromethylnaphthalenes and derived compounds.
Gething B, et al.
Journal of the Chemical Society, 190-193 (1962)
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