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Sigma-Aldrich

Lithium hydroxide monohydrate

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99.95% trace metals basis

Synonyme(s) :

Lithine hydrate

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About This Item

Formule linéaire :
LiOH · H2O
Numéro CAS:
Poids moléculaire :
41.96
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Pureté

99.95% trace metals basis

Forme

crystalline

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Impuretés

≤550.0 ppm Trace Metal Analysis

Application(s)

battery manufacturing

Autre catégorie plus écologique

Chaîne SMILES 

[Li+].O.[OH-]

InChI

1S/Li.2H2O/h;2*1H2/q+1;;/p-1

Clé InChI

GLXDVVHUTZTUQK-UHFFFAOYSA-M

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Description générale

Lithium hydroxide monohydrate is a strongly alkaline crystalline solid soluble in water. It is prepared industrially by recovering it from spodumene or by evaporating a solution prepared by reacting calcium hydroxide and lithium carbonate. It is mainly used in the synthesis of cathode materials for lithium-ion batteries, such as lithium cobalt oxide (LiCoO2) and lithium iron phosphate. It is also preferred over lithium carbonate for producing lithium nickel manganese cobalt oxides.
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Application

Lithium hydroxide monohydrate can be used mainly for the synthesis of cathode materials for Lithium-ion batteries:
  • To synthesize Olivine LiFePO4 nanoplates with different crystal orientations by glycol-based solvothermal process. It demonstrated that the crystal orientation of cathode nanoplates plays an important role in the performance.
  • As a precursor for the synthesis of LiFePO4 platelets under hydrothermal synthesis conditions. It exhibited homogeneous particle size distribution, greater electrochemical performances and cycle life, and morphology control.
  • To synthesize Ni-rich Li[NixCoyMn1–x–y]O2 gradient cathodes (NCM). These cathodes exhibited enhanced cycling and chemical stability due to their strong crystallographic texture, unique particle morphology, and highly correlated particle orientation.
  • As a precursor to prepare porous salt hydrate-based composites for low-temperature thermochemical heat storage.
  • As an electrolyte additive in lithium-ion batteries.
Our Lithium hydroxide monohydrate which is water soluble, with a purity of 99.95%, is an excellent choice as a source for Lithium to synthesize the cathode materials for Lithium-ion batteries. The high purity on trace metals basis makes it highly suitable for cathode formation, ensuring optimal electrochemical performance.

Pictogrammes

CorrosionExclamation mark

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8B - Non-combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Mechanism for Hydrothermal Synthesis of LiFePO4 Platelets as Cathode Material for Lithium-Ion Batteries
Xue Qin, et al.
The Journal of Physical Chemistry C, 114, 16806-16812 (2010)
High-Energy Ni-Rich Li [Ni x Co y Mn1--x--y] O2 Cathodes via Compositional Partitioning for Next-Generation Electric Vehicles
Chong S Yoon, et al
Chemistry of Materials, 29, 10436-10445 (2017)
Viktoria V Sursyakova et al.
Electrophoresis, 39(8), 1079-1085 (2018-02-08)
Cyclodextrins (CD) form inclusion complexes with different "guests" owing to the fact that the shape of the CD molecule is a truncated cone with a hydrophobic cavity. The adducts of CD with metal complexes remain scantily explored. In this study
Crystal Orientation Tuning of LiFePO4 Nanoplates for High Rate Lithium Battery Cathode Materials
Li Wang, et al
Nano Letters, 12, 5632-5636 (2012)
Effect of adding cerium to lithium on the performance of discharge and hydrogen evolution of the lithium anode
Ziyan Zhang, et al.
Journal of Electroanalytical Chemistry, 645, 81-86 (2010)

Articles

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

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