D93503
Silver diethyldithiocarbamate
ACS reagent, 99%
Synonym(s):
DETC, Diethyldithiocarbamic acid silver salt
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About This Item
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grade
ACS reagent
Quality Level
Assay
99%
form
powder
reaction suitability
core: silver
reagent type: catalyst
mp
172-175 °C (lit.)
storage temp.
2-8°C
SMILES string
CCN(CC)C(=S)S[Ag]
InChI
1S/C5H11NS2.Ag/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1
InChI key
NSVHDIYWJVLAGH-UHFFFAOYSA-M
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General description
Silver diethyldithiocarbamate is used to introduce diethyldithiocarbamato ligand and for the determination of arsenic.
Application
Reagent for the detection of arsenic and for the introduction of the diethyldithiocarbamato ligand.
Silver diethyldithiocarbamate (AgDDC) may be used in the preparation of adducts of triorganophosphines and diphosphines.
Also used for colorimetric determination of small quantities of arsenic
Spin trap used in conjunction with Fe2+ to detect NO in brain, kidney, liver, and other tissues. Simultaneous direct measurement of NO* and pO2 has been reported. A copper chelator, it has been used to quantitate copper in biological materials by ESR and is an inhibitor of superoxide dismutase, ascorbate oxidase, and other enzymes.
Biochem/physiol Actions
Inhibits induction of macrophage nitric oxide synthase.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Chem. Abstr., 117, 219549d-219549d (1992)
Evaluation of electrochemical hydride generation for spectrophotometric determination of As (III) by silver diethyldithiocarbamat
Talanta, 52, 1007-1014 (2000)
Inorganic Chemistry, 32, 3565-3565 (1993)
Hunjing Baohu, 23-23 (1991)
Synthesis and structural characterization of adducts of silver (I) diethyldithiocarbamate with P-donor ligands.
Inorgorganica Chimica Acta, 360(9), 2935-2943 (2007)
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