80833

18-Crown-6

suitable for ion chromatography, ≥99.0% (GC)

• Sinónimos: 1,4,7,10,13,16-Hexaoxacyclooctadecane
• Fórmula empírica (notación de Hill): C₁₂H₂₄O₆
• Número CAS: 17455-13-9
• Peso molecular: 264.32
• EC Number: 241-473-5
• UNSPSC Code: 12352005
• NACRES: NB.21
• Beilstein/REAXYS Number: 1619616
• MDL number: MFCD00005113
• Assay: ≥99.0% (GC)
• Form: solid

Propiedades

• Quality Segment: 100
• assay: ≥99.0% (GC)
• form: solid
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product, Sustainability features
• technique(s): ion chromatography: suitable
• mp: 42-45 °C (lit.)
• cation traces: Al: ≤1 mg/kg, Ba: ≤1 mg/kg, Bi: ≤1 mg/kg, Ca: ≤1 mg/kg, Cd: ≤1 mg/kg, Co: ≤1 mg/kg, Cr: ≤1 mg/kg, Cu: ≤1 mg/kg, Fe: ≤1 mg/kg, K: ≤20 mg/kg, Li: ≤1 mg/kg, Mg: ≤1 mg/kg, Mn: ≤1 mg/kg, Mo: ≤1 mg/kg, NH₄⁺: ≤10 mg/kg, Na: ≤20 mg/kg, Ni: ≤1 mg/kg, Pb: ≤1 mg/kg, Sr: ≤1 mg/kg, Zn: ≤1 mg/kg
• greener alternative category: , Aligned
• SMILES string: O1CCOCCOCCOCCOCCOCC1
• InChI: 1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
• InChI key: XEZNGIUYQVAUSS-UHFFFAOYSA-N

Descripción

General description

18-Crown-6 belongs to the class of Crown ethers, a group of macrocyclic polyethers, which have become valuable tools in organic synthesis, since they can solvate alkali, alkaline-earth and transition-metal cations in nonpolar, aprotic solvents. 18-Crown-6 is found to be most suitable for complexing with K⁺, NH₄⁺ and Rb⁺ cations.

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Application

Puede ser útil como catalizador de transferencia de fase.

Learn more in the Product Information

18-Crown-6 may be used as a complexing agent, along with the mobile phase for the separation of alkali and alkaline earth metal and amine cations and its application for the direct analysis of ammonia from nitrogenase is studied. It may also be used as a complexing agent in the determination of inorganic and organic anions, alkali, alkaline earth and transition metal cations by capillary electrophoresis using contactless conductometric detector.

Other Notes

Poliéteres macrocíclicos con repetición de unidades (-CH₂CH₂O). Los compuestos son ionofóricos (forman compuestos estables con cationes).

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• Pictogramas: GHS07
• Palabra de advertencia: Warning
• Códigos de peligro: H302
• Indicaciones de precaución: P301 + P312 + P330
• Hazard Classifications: Acute Tox. 4 Oral
• Clase de almacenamiento: 11 - Combustible Solids
• ¿Qué está pasando?: WGK 3
• Punto de inflamación (°F): Not applicable
• Punto de inflamación (°C): Not applicable