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759163

Sigma-Aldrich

P(o-tol)3 Pd G2

85%

Synonym(s):

Chloro[tri(o-tolyl)phosphine][2-(2′-amino-1,1′-biphenyl)]palladium(II)

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About This Item

Empirical Formula (Hill Notation):
C33H31ClNPPd
CAS Number:
1416422-78-0
Molecular Weight:
614.45
MDL number:
MFCD22417213
UNSPSC Code:
12161600
PubChem Substance ID:
329766758
NACRES:
NA.22

Quality Level

100

Assay

85%

form

solid

feature

generation 2

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

impurities

≤10% Acetone

mp

159-191 °C (decomposition)

SMILES string

CC1=CC=CC=C1P(C2=CC=CC=C2C)C3=CC=CC=C3C.NC4=C(C5=C([Pd]Cl)C=CC=C5)C=CC=C4

InChI

1S/C21H21P.C12H10N.ClH.Pd/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h4-15H,1-3H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1

InChI key

MNKLPYUHUVVRNW-UHFFFAOYSA-M

Related Categories

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Precautionary Statements

P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBR9213
SHBR6887
SHBC9543V
SHBC2561

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Articles

2nd Generation Buchwald Precatalysts

Buchwald precatalysts and ligands are bulky electron-rich dialkylbiaryl phospine-based catalysts and structurally related ligands that improve reactivity in Pd-catalyzed cross - coupling reactions

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