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686271

(S)-4-Chloro-α-methylbenzyl alcohol

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Synonym(s):

(S)-1-(4-Chlorophenyl)ethanol, (S)-4′-Chloro-1-phenylethanol

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1 g
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CLP 145,000

About This Item

Linear Formula:
ClC6H4CH(CH3)OH
CAS Number:
Molecular Weight:
156.61
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Assay:
95%
Form:
liquid

CLP 145,000

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Quality Segment

assay

95%

form

liquid

optical activity

[α]20/D -48.0°, c = 1 in chloroform

refractive index

n20/D 1.544

density

1.175 g/mL at 25 °C

functional group

chloro, hydroxyl

SMILES string

C[C@H](O)c1ccc(Cl)cc1

InChI

1S/C8H9ClO/c1-6(10)7-2-4-8(9)5-3-7/h2-6,10H,1H3/t6-/m0/s1

InChI key

MVOSNPUNXINWAD-LURJTMIESA-N

Application

(S)-4-Chloro-α-methylbenzyl alcohol can be used as a chiral building block in:
  • The enantioselective synthesis of (-)-(S,S)-clemastine.
  • The enantioselective and geometrically defined synthesis of chloro methylbenzyl pinacol boronic ester via lithiation−borylation methodology.


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This Item
323144319856
description

95%

description

98%

description

99 atom % D

assay

95%

assay

98%

assay

99% (CP)

Quality Level

100

Quality Level

100

Quality Level

200

refractive index

n20/D 1.544

refractive index

-

refractive index

n20/D 1.5335 (lit.)

density

1.175 g/mL at 25 °C

density

-

density

1.073 g/mL at 25 °C

form

liquid

form

-

form

-

optical activity

[α]20/D -48.0°, c = 1 in chloroform

optical activity

[α]20/D −40°, c = 5 in ethanol

optical activity

-


Pictograms

Exclamation mark

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

>230.0 °F

Flash Point (°C)

> 110 °C

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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