394505
Xenon difluoride
99.99% trace metals basis
Synonym(s):
Xenon Fluoride (XeF2)
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About This Item
Linear Formula:
XeF2
CAS Number:
Molecular Weight:
169.29
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
vapor pressure
3.8 mmHg ( 25 °C)
Quality Level
Assay
99.99% trace metals basis
form
crystals
mp
129 °C (lit.)
density
4.32 g/mL at 25 °C (lit.)
SMILES string
F[Xe]F
InChI
1S/F2Xe/c1-3-2
InChI key
IGELFKKMDLGCJO-UHFFFAOYSA-N
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General description
Xenon fluoride may be obtained by interacting elemental xenon and fluorine in the temperature range of 473-523 oC and 5 absolute atmosphere. Xenon difluoride readily interacts with Lewis acid and forms complexes.
Application
Very useful fluorination agent. Xenon fluoride may be used as a fluorinating agent to analyze sulphur, selenium and tellurium by gas chromatography.
Packaging
Packaged in PFA/FEP bottles
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Fluorination with XeF(2).(1) 44. Effect of Geometry and Heteroatom on the Regioselectivity of Fluorine Introduction into an Aromatic Ring.
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Infrared spectra of complex compounds of xenon difluoride with ruthenium pentafluoride
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Journal of Applied Spectroscopy, 17(1), 920-922 (1972)
Use of Xenon difluoride for the determination of sulfur, selenium and tellurium as the volatile fluorides by gas chromatography
Aleinikov NN, et al.
Russian Chemical Bulletin, 22(11), 2552-2554 (1973)
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Angewandte Chemie (International ed. in English), 48(8), 1432-1434 (2009-01-14)
Noble molecule: [Mg(XeF(2))(XeF(4))](AsF(6))(2) is the first coordination compound in which XeF(4) acts as a ligand to a metal center. It is also the first known compound, in which XeF(2) and XeF(4) are simultaneously coordinated to the same metal center (see
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