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Sigma-Aldrich

1,2-Epoxy-3-phenoxypropane

99%

Synonym(s):

2,3-Epoxypropyl phenyl ether, Glycidyl phenyl ether, Phenyl glycidyl ether

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About This Item

Empirical Formula (Hill Notation):
C9H10O2
CAS Number:
Molecular Weight:
150.17
Beilstein:
2744
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

vapor density

5.2 (vs air)

vapor pressure

0.03 mmHg ( 20 °C)

Assay

99%

form

liquid

refractive index

n20/D 1.53 (lit.)
n20/D 1.530 (lit.)

bp

245 °C (lit.)

mp

3.5 °C (lit.)

density

1.109 g/mL at 25 °C (lit.)

SMILES string

C1OC1COc2ccccc2

InChI

1S/C9H10O2/c1-2-4-8(5-3-1)10-6-9-7-11-9/h1-5,9H,6-7H2

InChI key

FQYUMYWMJTYZTK-UHFFFAOYSA-N

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Application

  • Stable Fe (III) phenoxyimines as selective and robust CO2/epoxide coupling catalysts: This paper discusses the catalytic performance of Fe(III) phenoxyimines with 1,2-epoxy-3-phenoxypropane (Fazekas et al., 2018).

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Carc. 1B - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

237.2 °F - closed cup

Flash Point(C)

114 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Jung-Hee Woo et al.
Journal of bioscience and bioengineering, 109(6), 539-544 (2010-05-18)
As a continuous effort of developing highly enantioselective epoxide hydrolase from marine microorganisms, it was found that Maritimibacter alkaliphilus KCCM 42376 [corrected] was highly enantioselective toward racemic glycidyl phenyl ether (GPE). An open reading frame (ORF) encoding a putative epoxide
Ida B Niklasson et al.
Chemical research in toxicology, 22(11), 1787-1794 (2009-09-04)
Epoxy resins can be prepared from numerous chemical compositions. Until recently, alternatives to epoxy resins based on diglycidyl ethers of bisphenol A (DGEBA) or bisphenol F (DGEBF) monomers have not received commercial interest, but are presently doing so, as epoxy
Manfred T Reetz et al.
Organic letters, 6(2), 177-180 (2004-01-16)
[reaction: see text] The epoxide hydrolase (EH) from Aspergillus niger, which shows a selectivity factor of only E = 4.6 in the hydrolytic kinetic resolution of glycidyl phenyl ether, has been subjected to directed evolution for the purpose of enhancing
M Garrido et al.
Analytica chimica acta, 585(2), 277-285 (2007-03-28)
This paper reports the validation of the results obtained by combining near infrared spectroscopy and multivariate curve resolution-alternating least squares (MCR-ALS) and using high performance liquid chromatography as a reference method, for the model reaction of phenylglycidylether (PGE) and aniline.
Fiona C Binks et al.
Polymers, 11(4) (2019-04-13)
The reaction of phenyl glycidyl ether (PGE) with 1-ethyl-3-methylimidazolium acetateand 1-ethyl-3-methylimidazolium thiocyanate to initiate the polyetherification reaction wasexamined using thermal and spectral analysis techniques. The influence of the nucleophilicity of theanions on the deprotonation of the 1-ethyl-3-methylimidazolium cation determined the

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