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701742

Sigma-Aldrich

Copper(I) chloride - bis(lithium chloride) complex

1 M in THF

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About This Item

Linear Formula:
CuCl · 2LiCl
Molecular Weight:
183.79
UNSPSC Code:
12161600
PubChem Substance ID:
329762317
NACRES:
NA.22

form

liquid

reaction suitability

core: copper
reagent type: catalyst

concentration

1 M in THF

refractive index

n20/D 1.442

density

1.015 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.Cl[Cu]

InChI

1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3

InChI key

QJRAZNXUNZEAQH-UHFFFAOYSA-K

Application

Solution used in Cu(I) transmetallation for amination reaction

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

62.6 °F

Flash Point(C)

17.0 °C

Certificates of Analysis (COA)

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Kienle, M. et al.
Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Vicente Del Amo et al.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)

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