67873
4-Methylmorpholine N-oxide monohydrate
≥95.0% (N)
Synonym(s):
4-Methylmorpholine 4-oxide monohydrate, 4-Methylmorpholine oxide monohydrate, N-Methylmorpholine N-oxide monohydrate, N-Methylmorpholine oxide monohydrate
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About This Item
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Quality Level
Assay
≥95.0% (N)
mp
71-75 °C
functional group
ether
SMILES string
O.C[N+]1([O-])CCOCC1
InChI
1S/C5H11NO2.H2O/c1-6(7)2-4-8-5-3-6;/h2-5H2,1H3;1H2
InChI key
WAZPLXZGZWWXDQ-UHFFFAOYSA-N
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Application
4-Methylmorpholine N-oxide (MNO) monohydrate can be used:
- As a reagent in the dihydroxylation and aminohydroxylation of olefins in the presence of osmium tetroxide (OsO4) catalyst.
- In the selective oxidation of sulphides to sulfoxides or sulfones in the presence of manganese and copper complexes with tetradentate ligands.
Other Notes
Reagent for an improved catalytic OsO4 oxidation of olefins to cis-1,2-diols; Review; For a ruthenium catalysed oxidation of alcohols to aldehydes and ketones
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Repr. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A New Approach to Osmium-Catalyzed Asymmetric Dihydroxylation and Aminohydroxylation of Olefins
Angewandte Chemie (International Edition in English), 41(3), 472-475 (2002)
Homogeneous and encapsulated within the cavities of zeolite Y chiral manganese and copper complexes with C2-multidentate ligands as catalysts for the selective oxidation of sulphides to sulfoxides or sulfones
J. Mol. Catal. A: Chem., 178(1-2), 253-266 (2002)
Tetrahedron Letters, 2503-2503 (1976)
Tetrahedron Letters, 1973-1973 (1976)
Chemical Reviews, 80, 187-187 (1980)
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