414336
Azetidine hydrochloride
97%
Synonym(s):
Trimethyleneimine hydrochloride
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About This Item
Empirical Formula (Hill Notation):
C3H7N · HCl
CAS Number:
Molecular Weight:
93.56
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
mp
>300 °C (lit.)
SMILES string
Cl[H].C1CNC1
InChI
1S/C3H7N.ClH/c1-2-4-3-1;/h4H,1-3H2;1H
InChI key
HGQULGDOROIPJN-UHFFFAOYSA-N
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Related Categories
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
305.6 °F
Flash Point(C)
152 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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1,5-/1,6-Allenals conjugated to an aromatic ring undergo a cyclization, in the presence of an amine, that leads to tricyclic compounds including the 1-aminotetralin scaffold. This domino process combines the in situ formation of the enamine and the cyclization affording the
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[reaction: see text] Hydroxylation of N-substituted azetidines 11 and 12 and piperidines 15-19 with Sphingomonas sp. HXN-200 gave 91-98% of the corresponding 3-hydroxyazetidines 13 and 14 and 4-hydroxypiperidines 20-24, respectively, with high activity and excellent regioselectivity. High yields and high
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