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Pyrrolopyrrole aza-BODIPY analogues: a facile synthesis and intense fluorescence.

Chemical communications (Cambridge, England) (2013-01-23)
Soji Shimizu, Taku Iino, Yasuyuki Araki, Nagao Kobayashi
ABSTRACT

Pyrrolopyrrole aza-BODIPY analogues were synthesized from diketopyrrolopyrrole and heteroaromatic amines in the presence of titanium tetrachloride. These novel compounds exhibit intense absorption in the visible region and strong emission with high fluorescence quantum yields greater than 0.8.

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Sigma-Aldrich
Titanium(IV) chloride, ReagentPlus®, 99.9% trace metals basis
Sigma-Aldrich
Titanium(IV) chloride solution, 1.0 M in methylene chloride
Sigma-Aldrich
Titanium(IV) chloride solution, 0.09 M in 20% HCl
Sigma-Aldrich
Titanium tetrachloride, packaged for use in deposition systems