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207802

Sigma-Aldrich

Potassium dichromate

ACS reagent, ≥99.0%

Sinonimo/i:

Potassium bichromate

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CHF 56.10
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CHF 193.00

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Spedizione prevista il09 aprile 2025


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100 G
CHF 56.10
500 G
CHF 193.00

About This Item

Formula condensata:
K2Cr2O7
Numero CAS:
Peso molecolare:
294.18
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NB.24
Saggio:
≥99.0%
Grado:
ACS reagent
Stato:
crystals

CHF 56.10


Spedizione prevista il09 aprile 2025


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Grado

ACS reagent

Livello qualitativo

Saggio

≥99.0%

Stato

crystals

Impiego in reazioni chimiche

reagent type: oxidant

Impurezze

≤0.005% insolubles

Perdita

≤0.05% loss on drying

pH

3.5-5.0 (25 °C, 29.4 g/L)

Punto di fusione

398 °C (lit.)

Anioni in tracce

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

Cationi in tracce

Ca: ≤0.003%
Na: ≤0.001%
Na: ≤0.02%
heavy metals (as Pb): ≤5 ppm

Stringa SMILE

[K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O

InChI

1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1
KMUONIBRACKNSN-UHFFFAOYSA-N

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Descrizione generale

Potassium dichromate is a red-orange colored solid. Its crystals belong to the triclinic crystal system. On heating above 600°C, it decomposes to give oxygen, potassium chromate and chromium(III) oxide. It acts as a strong oxidizing agent in acidic media. It can be synthesized by the fusion of chromium(III) oxide with potassium carbonate and nitrate or oxygen.[1]

Applicazioni

Potassium dichromate may be used in the preparation of hybride polymer-clay nanocomposite supported dichromate reagents.[2] It may also be used as an oxidant for the selective oxidation of primary and secondary alcohol to corresponding aldehydes and ketones, respectively.[3]

Avvertenze

Danger

Classi di pericolo

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

Organi bersaglio

Cardio-vascular system, Respiratory system

Codice della classe di stoccaggio

5.1B - Oxidizing hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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