D27802

1,4-Diazabicyclo[2.2.2]octane

ReagentPlus^®, ≥99%

• Sinonimo/i: TED, Triethylenediamine
• Formula empirica (notazione di Hill): C₆H₁₂N₂
• Numero CAS: 280-57-9
• Peso molecolare: 112.17
• Beilstein: 103618
• Numero CE: 205-999-9
• Numero MDL: MFCD00006689
• Codice UNSPSC: 12352100
• ID PubChem: 57654087
• NACRES: NA.21

Proprietà

• Tensione di vapore: 2.9 mmHg ( 50 °C)
• Livello qualitativo: 200
• Nome Commerciale: ReagentPlus^®
• Saggio: ≥99%
• Forma fisica: crystals
• Caratteristiche più verdi: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Indice di rifrazione: n20/D 1.4634 (lit.)
• Punto di fusione: 156-159 °C (lit.)
• Densità: 1.02 g/mL at 25 °C (lit.)
• Categoria alternativa più verde: , Aligned
• Stringa SMILE: N12CCN(CC2)CC1
• InChI: 1S/C6H12N2/c1-2-8-5-3-7(1)4-6-8/h1-6H2; IMNIMPAHZVJRPE-UHFFFAOYSA-N

Descrizione

Descrizione generale

1,4-Diazabicyclo[2.2.2]octane (DABCO) is a bicyclic compound used as a strong base and catalyst in organic synthesis.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

1,4-Diazabicyclo[2.2.2]octane (DABCO, triethylenediamine), a caged tertiary diamine, is a commonly used strong hindered amine base in chemical synthesis. It can also be employed as a complexing ligand and as a catalyst. Its gas-phase electronic absorption spectrum, vibrational spectra, multiphoton ionization (MPI), and two-photon fluorescence excitation (TPFE) spectra have been recorded and analyzed. Proton magnetic resonance (PMR) studies of DABCO in solid state were conducted in order to determine its line width, second moment, and spin-lattice relaxation time.

Applicazioni

1,4-Diazabicyclo[2.2.2]octane (DABCO) may be used in the synthesis of isoxazole derivatives via dehydration of primary nitro compounds in the presence of dipolarophiles. DABCO may be used in the preparation of the following:

• DABCO bis(perhydrate)
• DABCO monohydrate
• DABCO hexahydrate

Note legali

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Informazioni sulla sicurezza

• Pittogrammi: GHS02,GHS05,GHS07
• Avvertenze: Danger
• Indicazioni di pericolo: H228,H302,H315,H318
• Consigli di prudenza: P210 - P240 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Sol. 1 - Skin Irrit. 2
• Codice della classe di stoccaggio: 4.1B - Flammable solid hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 1
• Punto d’infiammabilità (°F): 144.0 °F - closed cup
• Punto d’infiammabilità (°C): 62.2 °C - closed cup
• Dispositivi di protezione individuale: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges