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Merck
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Documenti

B22984

Sigma-Aldrich

O-Benzylhydroxylamine hydrochloride

99%

Sinonimo/i:

Benzyloxyamine hydrochloride

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About This Item

Formula condensata:
C6H5CH2ONH2 · HCl
Numero CAS:
2687-43-6
Peso molecolare:
159.61
Beilstein:
3687991
Numero CE:
220-249-0
Numero MDL:
MFCD00012952
Codice UNSPSC:
12352100
ID PubChem:
24891644
NACRES:
NA.22

Saggio

99%

Forma fisica

crystals

Punto di fusione

238 °C (subl.) (lit.)

Stringa SMILE

Cl.NOCc1ccccc1

InChI

1S/C7H9NO.ClH/c8-9-6-7-4-2-1-3-5-7;/h1-5H,6,8H2;1H
HYDZPXNVHXJHBG-UHFFFAOYSA-N

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Applicazioni

Effective reagent used to prepare α-hydroxybenzylamines from α-hydroxyketones.

Pittogrammi

CorrosionExclamation mark
GHS05,GHS07

Avvertenze

Danger

Indicazioni di pericolo

H315,H317,H318

Classi di pericolo

Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

Certificati d'analisi (COA)

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Yin Luo et al.
ChemMedChem, 7(9), 1587-1593 (2012-07-20)
Forty-three oxime derivatives were synthesized by allowing O-benzylhydroxylamines to react with primary benzaldehydes or salicylaldehydes; these products were gauged as potential inhibitors of β-ketoacyl-(acyl-carrier-protein) synthase III (FabH). Among the 43 compounds, 38 are reported herein for the first time. These
G Cardillo et al.
Organic letters, 3(8), 1165-1167 (2001-05-12)
[reaction: see text]. The 1,4-addition of O-benzylhydroxylamine to alpha,beta-unsaturated imide 1 in the presence of BF3.Et2O proceeds with the preferential attack of the nucleophile on the Cbeta-re face. To explain this unexpected reactivity 1H, 13C, and 11B NMR investigations have
[Thermographic analysis of precipitates formed by the interaction of active ingredients and additives].
G Stampf et al.
Acta pharmaceutica Hungarica, 53(6), 268-272 (1983-11-01)
Han Fu et al.
Journal of combinatorial chemistry, 9(5), 804-810 (2007-08-11)
A highly regioselective and traceless solid-phase route to 1,7,8-trisubstituted purines has been developed. This methodology could be extended to the preparation of 8-azapurines and [i]-condensed purines. A representative set of 17 purines, azapurines, and [i]-condensed purines was synthesized. This paper
Samia Far et al.
Journal of peptide science : an official publication of the European Peptide Society, 11(7), 424-430 (2005-01-11)
The synthesis of glyoxylyl peptides by coupling the masked glyoxylic acid derivative (FmocNH)(2)CHCO(2)H, 1, to a peptidyl resin assembled using Fmoc/tert-butyl chemistry has been described recently. Deprotection and cleavage of the peptide from the solid support using TFA was followed
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