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690872

Sigma-Aldrich

Basolite® F300

greener alternative

produced by BASF

Sinonimo/i:

Fe-BTC, Iron 1,3,5-benzenetricarboxylate

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10 G
CHF 235.00
100 G
CHF 1’610.00

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Cambia visualizzazione
10 G
CHF 235.00
100 G
CHF 1’610.00

About This Item

Formula empirica (notazione di Hill):
C9H3FeO6
Numero CAS:
1195763-37-1
Peso molecolare:
262.96
Numero MDL:
MFCD11656051
Codice UNSPSC:
26111700
ID PubChem:
329761369
NACRES:
NA.23

CHF 235.00

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Grado

produced by BASF

Stato

solid

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Area superficiale

120-190 m2/g

Densità bulk

0.16‑0.35 g/cm3

Categoria alternativa più verde

, Enabling

Stringa SMILE

O=C1O[Fe]2OC(=O)c3cc1cc(c3)C(=O)O2

InChI

1S/C9H6O6.Fe/c10-7(11)4-1-5(8(12)13)3-6(2-4)9(14)15;/h1-3H,(H,10,11)(H,12,13)(H,14,15);/q;+3/p-3
UTYFBNKMZYRAFO-UHFFFAOYSA-K

Categorie correlate

Descrizione generale

Basolite®F300 (Fe-BTC) is a porous metal organic framework (MOF) that is used as a highly active catalyst for Lewis acid reactions such as acetalization of aldehydes and aldol condensation. It has a hybrid supertetrahedral build up from oxocentered trimmers of iron(III) octahedron that are connected by trimesate anions.[1]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Applicazioni

Fe-BTC based MOF can be used in greener applications such as energy storage through lithium ion batteries. It can also be used in the supercritical adsorption of CO2.[2][3][4]

Note legali

Basolite is a registered trademark of BASF SE

Pittogrammi

Health hazardExclamation mark
GHS08,GHS07

Avvertenze

Warning

Indicazioni di pericolo

H302,H315,H319,H371

Classi di pericolo

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 2

Organi bersaglio

Eyes,Central nervous system

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificati d'analisi (COA)

Lot/Batch Number
STBJ5843
STBD9968V
S61151V
S61151
S58688

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A combined computational and experimental study of high pressure and supercritical CO2 adsorption on Basolite MOFs
Deniz E, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 175(115), 34-42 (2013)
Facile synthesis of the Basolite F300-like nanoscale Fe-BTC framework and its lithium storage properties
Hu X, et al.
Royal Society of Chemistry Advances, 6(115), 114483-114490 (2016)
Comparison of porous iron trimesates basolite F300 and MIL-100 (Fe) as heterogeneous catalysts for lewis acid and oxidation reactions: roles of structural defects and stability
Dhakshinamoorthy A, et al.
ACS Catalysis, 2(10), 2060-2065 (2012)
Direct synthesis, structural features, and enhanced catalytic activity of the basolite F300-like semiamorphous Fe-BTC framework
Sanchez-Sanchez M, et al.
Crystal Growth & Design, 15(9), 4498-4506 (2015)
Vijaya Ravinayagam et al.
Saudi journal of biological sciences, 27(7), 1726-1736 (2020-06-23)
Drug resistant bacteria affects millions worldwide and remains a serious threat to health care system. The study reports the first application of hybrid nanocomposites based on zeolitic imidazolate framework-8 (ZIF-8) with MFI structured zeolite Ti-ZSM-5 (TiZ5) and mesoporous carbon (MC).
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Articoli

Metal Organic Frameworks (MOFs)

Metal-organic frameworks (MOFs) are porous, crystalline materials composed of metal ions bound by organic ligands.

Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. 物理的性質（例えば比表面積）の安定しているサンプルでしょうか？ 経時変化や劣化などはしないでしょうか？

    1 answer

    1. If the product is stored according to the SDS (i.e. tightly closed and dry), there should not be changes to the pore structure over time.

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