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Sigma-Aldrich

Polypyrrole

greener alternative

conductivity 10-50 S/cm (pressed pellet)

Sinonimo/i:

PPy

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5 G
CHF 200.00
25 G
CHF 518.00

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Cambia visualizzazione
5 G
CHF 200.00
25 G
CHF 518.00

About This Item

Numero CAS:
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.23

CHF 200.00


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Stato

solid

contiene

proprietary organic sulfonic acid as dopant

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Solubilità

H2O: insoluble
organic solvents: insoluble

Categoria alternativa più verde

Stringa SMILE

[nH]1cccc1

InChI

1S/C4H5N/c1-2-4-5-3-1/h1-5H
KAESVJOAVNADME-UHFFFAOYSA-N

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Descrizione generale

Polypyrrole (PPy) is a widely used highly conductive and highly stable heterocyclic polymer. It is majorly used in electrochemical applications. It is a cost-efficient conducting polymer that has a stable oxidation and high solubility in water. It exhibits a high degree of flexibility than polyaniline and has a density that facilitates a higher capacitance per unit volume.[1][2][3][4]
PPy may be prepared by a standard electrochemical technique.[5] It may also be prepared by reacting -napthalene sulfonic acid (NSA) and ammonium peroxo-disulfate in aqueous medium.[6] The charges on the surfaces can be easily modified by doping the polymer during its synthesis.[7] Solubility and conductivity measurements of PPy doped with camphor sulfonic and dodecyl benzene sulfonic acid have been reported.[8] Lectrosensitivity and lower oxidation potential of PPy make it potentially useful for drug delivery, chemical sensors, batteries, ion selective electrodes, biosensor and biochemistry research.[9]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product is used in energy conversion and storage, thus has been enhanced for energy efficiency. Click here for more information.

Applicazioni

Conducting polymer.
Conductive additive for thermoplasitics and thermosets.
Conductive additive for thermoplastics and thermosets. Polypropylene composites constitute the polymer electrolyte membrane fuel cell (PEMFC). Addition of PPy to polypropylene composites alters its conductivity.[7][10]
PPy can be used for a variety of applications such as:
  • electrode materials for sensors used in electrocardiography (ECG)[11]
  • formation of electrode material for a variety of energy storage applications[12]
  • encapsulation of lithium sulfide (Li2S) as a high performance cathode material[13]

PPy is mainly used in the fabrication of a variety of electrochemical devices, which include supercapacitors,[14][15] chemical sensors,[16] dye sensitized solar cells and lithium-ion batteries.[17]

Confezionamento

Packaged in glass bottles

Altre note

Stable up to at least 290°C in air

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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In-situ encapsulation of nickel nanoparticles in polypyrrole nanofibres with enhanced performance for supercapacitor
Muhamad SU, et al.
Electrochimica Acta, 249(8), 9-15 (2017)
Conducting polymers with superhydrophobic effects as anticorrosion coating
Intelligent Coatings for Corrosion Control, 409-430 (2014)
Sensors Based on Conducting Polymers for Measurement of Physiological Parameters
Teran-Jimenez O, et al.
IEEE Sensors Journal, 17(8), 2492-2497 (2017)
Conducting polymers with superhydrophobic effects as anticorrosion coating
Intelligent Coatings for Corrosion Control edited by Atul Tiwari, Lloyd Hihara, James Rawlins, 409-430 (2014)
Facile synthesis of Li 2 S-polypyrrole composite structures for high-performance Li 2 S cathodes
She ZW, et al.
Energy & Environmental Science, 7(2), 672-676 (2014)

Articoli

By altering the physicochemical properties, smart or intelligent drug delivery systems can be designed to deliver therapeutic molecules on-demand. Learn more about the application of stimuli-responsive materials in drug delivery.

The application of conducting polymers at the interface with biology is an exciting new trend in organic electronics research.

Self-healing soft electronic materials offer potential cost savings and reduced electronic waste.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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