332364

Allyltriphenylstannane

97%

• Sinonimo/i: 2-Propenyl-triphenylstannane, Allyltriphenyltin
• Formula condensata: CH₂=CHCH₂Sn(C₆H₅)₃
• Numero CAS: 76-63-1
• Peso molecolare: 391.09
• Beilstein: 3612762
• Numero CE: 200-975-4
• Numero MDL: MFCD00048162
• Codice UNSPSC: 12352103
• ID PubChem: 24859890
• NACRES: NA.22

Proprietà

• Saggio: 97%
• Stato: solid
• Punto di fusione: 71-74 °C (lit.)
• Stringa SMILE: C=CC[Sn](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/3C6H5.C3H5.Sn/c3*1-2-4-6-5-3-1;1-3-2;/h3*1-5H;3H,1-2H2;; NDUYAGLANMHJHF-UHFFFAOYSA-N

Descrizione

Descrizione generale

Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.[1]

Applicazioni

Allyltriphenylstannane can be used:

• As a reagent in the C-H phenylation of azoles catalyzed by palladium.[2]
• As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)₃.[3]
• As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.[4]

Informazioni sulla sicurezza

• Pittogrammi: GHS06,GHS09
• Avvertenze: Danger
• Indicazioni di pericolo: H301 + H311 + H331,H410
• Consigli di prudenza: P261 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Classi di pericolo: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Codice della classe di stoccaggio: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves, type N95 (US)