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201138

Sigma-Aldrich

Ammonio esafluorofosfato

≥95%

Sinonimo/i:

Ammonium hexafluophosphate, Ammonium hexafluorophosphate V, Ammonium phosphorus hexafluoride, Ammoniumhexafluorophosphate

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25 G
CHF 66.20
100 G
CHF 192.00
500 G
CHF 697.00

CHF 66.20

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25 G
CHF 66.20
100 G
CHF 192.00
500 G
CHF 697.00

About This Item

Formula condensata:
NH4PF6
Numero CAS:
16941-11-0
Peso molecolare:
163.00
Numero CE:
241-009-1
Numero MDL:
MFCD00064642
Codice UNSPSC:
12352302
eCl@ss:
38070413
ID PubChem:
24851996
NACRES:
NA.22

CHF 66.20

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Saggio

≥95%

Stato

solid

Concentrazione

≤100%

Solubilità

water: soluble ca.50 g/L

Densità

2.18 g/mL at 25 °C (lit.)

Stringa SMILE

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1
NIZXKAYXSNUDOU-UHFFFAOYSA-O

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Applicazioni

Ammonium hexafluorophosphate (NH4PF6) can be used as a precursor for the preparation of:
  • Metal complexes, particularly iridium and rhodium complexes.[1][2][3]       
  • Flame retardant cellulose-based materials.[4]       
  • Cyclic amidinium and iminium ammonium hexafluorophosphate salts.[5]        
  • The polymer-supported iridium isomerization catalyst for the selective trans isomerization of aryl allylic derivatives.[6]

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H314

Classi di pericolo

Skin Corr. 1B

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKCV7777
MKCT7095
MKCT4965
MKCS8358
MKCR4006

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A polymer-supported iridium catalyst for the stereoselective isomerisation of double bonds
Baxendale IR, et al.
Synlett, 2002(03), 0516-0518 (2002)
Preparations of iridium complexes containing phenanthroline ancillary ligands and electrical properties of cationic iridium-based light-emitting electrochemical cells
Park S, et al.
Surface and Interface Analysis : SIA, 44(11-12), 1479-1482 (2012)
Electronic absorption and emission spectral studies of square-planar Rhodium (I) and Iridium (I) complexes. Evidence for a charge-transfer emitting state
Geoffroy GL, et al.
Journal of the American Chemical Society, 96(10), 3105-3108 (1974)
A simple and efficient one-step protocol for the preparation of alkyl-substituted ammonium tetrafluoroborate and hexafluorophosphate salts
Saba Shahrokh, et al.
Journal of Fluorine Chemistry, 153, 168-171 (2013)
Accelerated luminophore discovery through combinatorial synthesis.
Lowry, Michael S et al.
Journal of the American Chemical Society, 126(43), 14129-14135 (2004)
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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