- Pd-catalyzed synthesis of allylic silanes from allylic ethers.
Pd-catalyzed synthesis of allylic silanes from allylic ethers.
Organic letters (2009-12-03)
Ralph Moser, Takashi Nishikata, Bruce H Lipshutz
PMID19950911
RÉSUMÉ
Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.
MATÉRIAUX