96096
Zeolite
Synonyme(s) :
Aluminosilicate
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About This Item
Numéro CAS:
Numéro CE :
Numéro MDL:
Code UNSPSC :
41123003
Nomenclature NACRES :
NA.25
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Description générale
Choosing a Molecular Sieve:
1. The preferential adsorption of one molecule over another depends upon pore diameter and mesh size.
2. The dynamic capacity of the silica gel for adsorbing a particular compound is governed by the internal surface area; the greater the surface area, the greater the dynamic capacity.
3. Rate of adsorption and sharpness of resolution are dependent chiefly on particle size and column packing; a fine particle size gives optimum sharpness of resolution.
4. Liquids are most readily adsorbed from solvents in which they are least soluble; a good solvent makes a good desorbing agent.
5. Highly polar liquids are readily adsorbed. Compounds having hydroxyl groups, or containing oxygen are strongly adsorbed.
6. For similar compounds, the higher the molecular weight the higher the selectivity.
7. For hydrocarbons of similar molecular weight, adsorptivity increases with the number of double bonds.
1. The preferential adsorption of one molecule over another depends upon pore diameter and mesh size.
2. The dynamic capacity of the silica gel for adsorbing a particular compound is governed by the internal surface area; the greater the surface area, the greater the dynamic capacity.
3. Rate of adsorption and sharpness of resolution are dependent chiefly on particle size and column packing; a fine particle size gives optimum sharpness of resolution.
4. Liquids are most readily adsorbed from solvents in which they are least soluble; a good solvent makes a good desorbing agent.
5. Highly polar liquids are readily adsorbed. Compounds having hydroxyl groups, or containing oxygen are strongly adsorbed.
6. For similar compounds, the higher the molecular weight the higher the selectivity.
7. For hydrocarbons of similar molecular weight, adsorptivity increases with the number of double bonds.
Regeneration or Activation:
A saturated molecular sieve can be restored to its original capacity by regeneration, the principle of which involves changing the conditions surrounding the adsorbent to correspond to a very low equilibrium capacity. In general, the greater the difference between the equilibrium capacities of adsorption and regeneration, the more rapid and complete the regeneration.
The sieve may be regenerated in one of four ways:
1. Thermal reactivation –The maximum regeneration temperature for Silica is 300°C.
2. Pressure reactivation
3. Passing an appropriate fluid through the gel bed at normal temperature and pressure.
4. Displacement of adsorbates by passing a high concentration of molecules in a fluid through the bed.
A saturated molecular sieve can be restored to its original capacity by regeneration, the principle of which involves changing the conditions surrounding the adsorbent to correspond to a very low equilibrium capacity. In general, the greater the difference between the equilibrium capacities of adsorption and regeneration, the more rapid and complete the regeneration.
The sieve may be regenerated in one of four ways:
1. Thermal reactivation –The maximum regeneration temperature for Silica is 300°C.
2. Pressure reactivation
3. Passing an appropriate fluid through the gel bed at normal temperature and pressure.
4. Displacement of adsorbates by passing a high concentration of molecules in a fluid through the bed.
Application
Zeolite, a microporous, aluminosilicate mineral, is used as a molecular sieve and as an adsorbent of a wide variety of cations, such as Na+, K+, Ca2+, Mg2+ and others. Zeolite is used in the development of a variety of bioreactor devices.
Autres remarques
In the determination of serum triglycerides
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
nwg
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
Eyeshields, Gloves, type N95 (US)
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Lactic acid production on liquid distillery stillage by Lactobacillus rhamnosus immobilized onto zeolite.
Djukic-Vukovic AP, Mojovic LV, Jokic BM, et al.
Bioresource Technology (2012)
Hossein Jahangirian et al.
International journal of nanomedicine, 15, 1005-1020 (2020-02-28)
The aim of this study was to prepare zeolite/iron (III) oxide nanocomposites (zeolite/Fe2O3-NCs) as a smart fertilizer to improve crop yield and soil productivity. Zeolite/Fe2O3-NCs were successfully produced by loading of Fe2O3-NPs onto the zeolite surface using a quick green
C Mery et al.
Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering, 47(3), 420-427 (2012-02-11)
An evaluation of natural zeolite as a microorganism carrier in nitrifying reactors operated in batch mode was carried out. Specifically, the influence of zeolite particle sizes of 0.5, 1.0 and 2.0 mm in diameter on microorganism adherence to zeolite, ammonium
Mehran Andalib et al.
Bioresource technology, 121, 411-418 (2012-08-07)
The primary objective of this work was to investigate the treatability of thin stillage as a by-product of bioethanol production plants using an anaerobic fluidized bed bioreactor (AFBR) employing zeolite with average diameter of (d(m)) of 425-610 μm and specific
Benzylimidazolium cations as zeolite structure-directing agents. Differences in performance brought about by a small change in size.
Rojas A, Gomez-Hortiguela L, Camblor MA.
Dalton Transactions (2012)
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