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439215

Sigma-Aldrich

Tetrahydrofurane

≥99.9%, suitable for HPLC, inhibitor-free

Synonyme(s) :

Oxolane, Oxyde de butylène, Oxyde de tétraméthylène

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About This Item

Formule empirique (notation de Hill):
C4H8O
Numéro CAS:
109-99-9
Poids moléculaire :
72.11
Numéro Beilstein :
102391
Numéro CE :
203-726-8
Numéro MDL:
MFCD00005356
Code UNSPSC :
12190000
ID de substance PubChem :
329756429

product name

Tetrahydrofurane, suitable for HPLC, ≥99.9%, inhibitor-free

Densité de vapeur

2.5 (vs air)

Niveau de qualité

100

Pression de vapeur

114 mmHg ( 15 °C)
143 mmHg ( 20 °C)

Pureté

≥99.9%

Forme

liquid

Température d'inflammation spontanée

610 °F

Limite d'explosivité

1.8-11.8 %

Technique(s)

HPLC: suitable

Impuretés

≤0.015% peroxide (as H2O2)
<0.02% water

Résidus d'évap.

<0.0005%

Indice de réfraction

n20/D 1.407 (lit.)

Point d'ébullition

65-67 °C (lit.)

Pf

−108 °C (lit.)

Solubilité

H2O: soluble

Densité

0.889 g/mL at 25 °C (lit.)

λ

H2O reference

Absorption UV

λ: 212 nm Amax: 1.0
λ: 250 nm Amax: 0.180
λ: 300 nm Amax: 0.020
λ: 350-400 nm Amax: 0.005

Chaîne SMILES 

C1CCOC1

InChI

1S/C4H8O/c1-2-4-5-3-1/h1-4H2

Clé InChI

WYURNTSHIVDZCO-UHFFFAOYSA-N

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Description générale

Tetrahydrofuran (THF) is a saturated cyclic ether with a potential use as a biofuel. Its combustion studies have been reported. Reports suggest it is a better promoter than 1,3 dioxolane for CO2-hydrate formation. The effect of THF on the biological systems has been studied.

Application

Tetrahydrofuran may be used as a solvent in the following processes:
  • Formation of diacetylinic polymers.
  • RAFT polymerization of p-acetoxystyrene.
  • Synthesis of di-tert-butyl-Phosphinoferrocene.
It may be used in the following processes:
  • As mobile phase solvent in high-performance liquid chromatography.
  • As a solvent in the preparation of spin-coated poly(bisphenol A decane ether).
  • Formation of butyrolactone (BTL) by green oxidation method.
  • As a solvent for lignin depolymerization to isolate phenolic monomer.

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Réf. du produit
Description
Tarif

Pictogrammes

FlameHealth hazardExclamation mark
GHS02,GHS08,GHS07

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Organes cibles

Central nervous system, Respiratory system

Risques supp

EUH019

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

-6.2 °F - closed cup

Point d'éclair (°C)

-21.2 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
SHBS2068
SHBR9044
SHBQ8762
SHBQ7798
SHBQ1184

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Tetrahydrofurane

Solène I Cauët et al.
Journal of polymer science. Part A, Polymer chemistry, 48(12), 2517-2524 (2010-07-27)
The kinetics of the RAFT polymerization of p-acetoxystyrene using a trithiocarbonate chain transfer agent, S-1-dodecyl-S'-(α,α'-dimethyl-α″-acetic acid)trithiocarbonate, DDMAT, was investigated. Parameters including temperature, percentage initiator, concentration, monomer-to-chain transfer agent ratio and solvent were varied and their impact on the rate of
Oxidation of tetrahydrofuran to butyrolactone catalyzed by iron-containing clay.
Ausavasukhi A and Sooknoi T.
Green Chemistry, 17(1), 435-441 (2015)
Novel Diacetylinic Aryloxysilane Polymers: A New Thermally Cross-Linkable High Temperature Polymer System.
Drake K, et al.
Macromolecules, 46(11), 4370-4377 (2013)
An efficient and economical process for lignin depolymerization in biomass-derived solvent tetrahydrofuran.
Long J, et al.
Bioresource Technology, 154, 10-17 (2014)
1,3 Dioxolane versus tetrahydrofuran as promoters for CO2-hydrate formation: Thermodynamics properties, and kinetics in presence of sodium dodecyl sulfate.
Torre JP, et al.
Chemical Engineering Science, 126, 688-697 (2015)
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