935638

Tris(trimethylsilyl) phosphate

≥99.0%, anhydrous, battery grade

• Synonyme(s) : Phosphoric acid tris(trimethylsilyl ester), TMSP, TMSPA
• Formule linéaire : [(CH₃)₃SiO]₃P(O)
• Numéro CAS: 10497-05-9
• Poids moléculaire : 314.54
• Numéro Beilstein : 1794624
• Numéro MDL: MFCD00008267
• Code UNSPSC : 12352005

Propriétés

• Qualité: battery grade
• Niveau de qualité: 100
• Description: Application: Battery manufacturing
• Pureté: ≥99.0%
• Forme: (colorless liquid)
• Caractéristiques du produit alternatif plus écologique: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Impuretés: ppm H2O≤500; ≤500 ppm H₂O
• Indice de réfraction: n20/D 1.409 (lit.)
• Point d'ébullition: 228-229 °C/720 mmHg (lit.); 228-229 °C
• Pf: 3-4 °C (lit.); 3-4 °C
• Densité: 0.945 g/mL at 25 °C (lit.)
• Application(s): battery manufacturing
• Autre catégorie plus écologique: Enabling
• Chaîne SMILES: C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C
• InChI: 1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
• Clé InChI: QJMMCGKXBZVAEI-UHFFFAOYSA-N

Description

Description générale

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Application

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF₆-based electrolytes at elevated temperatures.TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

Informations sur la sécurité

• Pictogrammes: GHS02,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225,H315,H319,H335
• Conseils de prudence: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 55.4 °F - closed cup
• Point d'éclair (°C): 13 °C - closed cup