778761

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine

≥95.0% (HPLC)

• Synonyme(s) : (S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene
• Formule empirique (notation de Hill): C₁₆H₁₆N₂
• Numéro CAS: 138517-66-5
• Poids moléculaire : 236.31
• Numéro Beilstein : 8693351
• Numéro MDL: MFCD09038519
• Code UNSPSC : 12352116
• ID de substance PubChem : 329767993
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: ≥95.0% (HPLC); 95.0-105.0% (NT)
• Forme: powder
• Pureté optique: enantiomeric excess: ≥98.0%
• Chaîne SMILES: N[C@H]1[C@H](N)[C@H]2c3ccccc3[C@@H]1c4ccccc24
• InChI: 1S/C16H16N2/c17-15-13-9-5-1-2-6-10(9)14(16(15)18)12-8-4-3-7-11(12)13/h1-8,13-16H,17-18H2/t13-,14+,15-,16-/m1/s1
• Clé InChI: NWDYSRZJOLDMRE-QKPAOTATSA-N

Description

Application

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:

• To synthesize pyridine based C₂-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
• To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
• To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

Conditionnement

Bottomless glass bottle. Contents are inside inserted fused cone.

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable