693979

(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane

90%

• Synonyme(s) : Glyoxal bis(2,6-diisopropylanil), N,N′-Bis(2,6-diisopropylphenyl)-1,4-diazabutadiene, N,N′-Bis(2,6-diisopropylphenyl)ethanediimine
• Formule linéaire : (C₃H₇)₂C₆H₃NCHCHNC₆H₃(C₃H₇)₂
• Numéro CAS: 74663-75-5
• Poids moléculaire : 376.58
• Numéro MDL: MFCD03838856
• Code UNSPSC : 12352300
• ID de substance PubChem : 329761636
• Nomenclature NACRES : NA.22

Propriétés

• Pureté: 90%
• Forme: solid
• Pertinence de la réaction: reagent type: ligand
• Pf: 105-109 °C
• Chaîne SMILES: CC(C)c1cccc(C(C)C)c1\N=C\C=N\c2c(cccc2C(C)C)C(C)C
• InChI: 1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3/b27-15+,28-16+
• Clé InChI: JWVIIGXMTONOFR-DPCVLPDWSA-N

Description

Application

• Reactant in preparation of derived ruthenium olefin metathesis catalysts
• N-cyclic carbene ligand

Catalyst in:

• Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands
• Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors
• N-arylation of aromatic amines
• Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable