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Sigma-Aldrich

Borane-ammonia complex

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95%

Synonyme(s) :

Amminetrihydroboron, Borazane

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About This Item

Formule linéaire :
H3N · BH3
Numéro CAS:
Poids moléculaire :
30.87
Numéro MDL:
Code UNSPSC :
26111700
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Pureté

95%

Forme

solid

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Design for Energy Efficiency
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Autre catégorie plus écologique

Chaîne SMILES 

B.N

InChI

1S/BH3.H3N/h2*1H3

Clé InChI

WZMUUWMLOCZETI-UHFFFAOYSA-N

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Description générale

Ammonia borane also known as borazane has high hydrogen content (about 20% mass). Thermal decomposition of borazane take place in the temperature range 350-410K accompanied by hydrogen release and heat evolution. It may find use as a hydrogen source in fuel cells in the future.
Borane-ammonia complex is a novel material, where ammonia is tightly bound to a ligand through all four of its atoms. It is a donor-acceptor complex that is formed by electron donated by a Lewis base (NH3) to a Lewis acid (BH3). It shows a B-N bond distance of 1.564 Å.
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Application

Borazane is popularly used as an ammonia borane (AB) source for the formation of hexagonal boron nitride monolayers which are used as a substrate for graphene growth.

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves


Certificats d'analyse (COA)

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Qiuxia Zhou et al.
Journal of colloid and interface science, 508, 542-550 (2017-09-05)
The design and fabrication of highly active and durable catalysts for the ammonia borane (AB) hydrolysis has been one of significant issues in the application of green and economic hydrogen energy. Nanoporous (NP) PtCo/Co
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Science advances, 6(10), eaay4958-eaay4958 (2020-03-18)
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The breaking of multiple symmetries by periodic lattice distortion at a commensurate charge density wave (CDW) state is expected to give rise to intriguing interesting properties. However, accessing the commensurate CDW state on bulk TaS2 crystals typically requires cryogenic temperatures
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Nanoscale, 12(41), 21138-21145 (2020-07-15)
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ACS nano, 13(4), 4530-4537 (2019-03-22)
The solid progress in the study of a single two-dimensional (2D) material underpins the development for creating 2D material assemblies with various electronic and optoelectronic properties. We introduce an asymmetric structure by stacking monolayer semiconducting tungsten disulfide, metallic graphene, and

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