334995

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

• Synonyme(s) : Carbonylchlorohydrotris(triphenylphosphine)ruthenium
• Formule linéaire : [(C₆H₅)₃P]₃Ru(CO)(Cl)H
• Numéro CAS: 16971-33-8
• Poids moléculaire : 952.40
• Numéro CE : 241-051-0
• Numéro MDL: MFCD00049804
• Code UNSPSC : 12161600
• ID de substance PubChem : 24860276
• Nomenclature NACRES : NA.22

Propriétés

• Pertinence de la réaction: core: ruthenium; reagent type: catalyst
• Pf: 204-206 °C (dec.) (lit.)
• Chaîne SMILES: Cl[Ru].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
• InChI: 1S/3C18H15P.CO.ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;/h3*1-15H;;1H;/q;;;;;+1/p-1
• Clé InChI: MVJRXTSUBHUUPN-UHFFFAOYSA-M

Description

Description générale

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is a coordination compound commonly used as a catalyst in organic synthesis reactions such as hydrogenation, transfer hydrogenative C-C bond-forming reactions, transfer hydrogenation, and α-alkylation of ketones with primary alcohols. In addition, it is used as a precursor of pincer ruthenium carbonyl catalysts for hydrogenation.

Application

• Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II): This ruthenium complex is used as a versatile catalyst for various reactions including hydrogenation, transfer hydrogenation, C-C bond-forming reactions, α-alkylation of ketones with primary alcohols, and as a precursor for pincer ruthenium carbonyl catalysts for hydrogenation. The complex is noted for its physical properties, such as decomposing above its melting point (204-206°C), and its solubility characteristics. It is very insoluble in water, ethanol, and DMSO, sparingly soluble in benzene and acetone, and slightly soluble in chloroform (Kuriyama, 2001).

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H302 + H312 + H332,H315,H319,H335
• Conseils de prudence: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: dust mask type N95 (US), Eyeshields, Gloves