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207780

Sigma-Aldrich

Copper

powder, <75 μm, 99%

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About This Item

Formule empirique (notation de Hill):
Cu
Numéro CAS:
Poids moléculaire :
63.55
Numéro CE :
Numéro MDL:
Code UNSPSC :
12141711
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Pureté

99%

Forme

powder

Résistivité

1.673 μΩ-cm, 20°C

Taille des particules

<75 μm

Point d'ébullition

2567 °C (lit.)

Pf

1083.4 °C (lit.)

Densité

8.94 g/mL at 25 °C (lit.)

Chaîne SMILES 

[Cu]

InChI

1S/Cu

Clé InChI

RYGMFSIKBFXOCR-UHFFFAOYSA-N

Description générale

Copperis a versatile and widely used metal with significant importance in variousfields, particularly in catalysis and material science. In material science,copper is used in various conductive materials due to its excellent electricaland thermal conductivity, ductility, and corrosion resistance. Additionally,copper is also extensively used as a catalyst in various chemical reactions dueto its ability to facilitate electron transfer and promote redox reactions. Itoften acts as a catalyst in various reactions which include reduction, cross-couplingreactions and “click" chemistry (such as copper-catalyzed azide-alkynecycloaddition reactions.

Application

  • Photoinduced Copper-Catalyzed Aminoalkylation of Amino-Pendant Olefins.: This study explores the use of copper catalysts in photoinduced aminoalkylation reactions, highlighting the efficiency and potential applications in organic synthesis (Zhang et al., 2023).
  • Synthesis of Azoxy Compounds: from Copper Compounds to Mesoporous Silica-Encaged Ultrasmall Copper Catalysts.: This research focuses on the development of copper-based catalysts for the synthesis of azoxy compounds, emphasizing their application in sustainable chemistry (Han et al., 2023).
  • Cu-catalyzed enantioselective allylic alkylation with organolithium reagents.: The paper presents a method for enantioselective allylic alkylation using copper catalysts, providing insights into asymmetric synthesis techniques (Hornillos et al., 2017).

Pictogrammes

FlameEnvironment

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Sol. 1

Code de la classe de stockage

4.1B - Flammable solid hazardous materials

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Daniel L Priebbenow et al.
Organic letters, 15(24), 6155-6157 (2013-11-28)
A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were
Hiroshi Sato et al.
Science (New York, N.Y.), 343(6167), 167-170 (2013-12-18)
Carbon monoxide (CO) produced in many large-scale industrial oxidation processes is difficult to separate from nitrogen (N2), and afterward, CO is further oxidized to carbon dioxide. Here, we report a soft nanoporous crystalline material that selectively adsorbs CO with adaptable
Magnus Andersson et al.
Nature structural & molecular biology, 21(1), 43-48 (2013-12-10)
Heavy metals in cells are typically regulated by PIB-type ATPases. The first structure of the class, a Cu(+)-ATPase from Legionella pneumophila (LpCopA), outlined a copper transport pathway across the membrane, which was inferred to be occluded. Here we show by
Yan Meng et al.
Biochimica et biophysica acta, 1690(3), 208-219 (2004-10-30)
Hepatic abnormalities in Long-Evans Cinnamon (LEC) rats, an animal model of Wilson disease (WD), were restored by the expression of the human ATP7B cDNA under the control of CAG promoter. Expression of ATP7B transcript and protein in the liver of
Seonah Kim et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(1), 149-154 (2013-12-18)
Lytic polysaccharide monooxygenases (LPMOs) exhibit a mononuclear copper-containing active site and use dioxygen and a reducing agent to oxidatively cleave glycosidic linkages in polysaccharides. LPMOs represent a unique paradigm in carbohydrate turnover and exhibit synergy with hydrolytic enzymes in biomass

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