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Supelco

Bromomethane solution

certified reference material, 200 μg/mL in methanol

Synonym(s):

Methyl bromide

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About This Item

Empirical Formula (Hill Notation):
CH3Br
CAS Number:
74-83-9
Molecular Weight:
94.94
MDL number:
MFCD00000166
UNSPSC Code:
12000000
PubChem Substance ID:
24871979

grade

certified reference material
TraceCERT®

product line

TraceCERT®

CofA

current certificate can be downloaded

packaging

ampule of 1 mL

concentration

200 μg/mL in methanol

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

single component solution

storage temp.

2-8°C

SMILES string

CBr

InChI

1S/CH3Br/c1-2/h1H3

InChI key

GZUXJHMPEANEGY-UHFFFAOYSA-N

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General description

Bromomethane is a broad spectrum fumigant, which can find applications in post-harvest fumigation and pest control of several foods like spices, cereals, nuts, dried fruits, fresh fruits, vegetables, turf and also nursery crops.
Bromomethane is frequently used as fumigant. It is a liquid at room temperature which readily vaporizes into a colourless gas. It is slightly soluble in water and is freely soluble in organic solvents.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Solution of bromomethane may be used in preparation of 2-methoxyisoindoline-1,3- dione.

Other Notes

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes,Central nervous system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

51.8 °F - closed cup

Flash Point(C)

11 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
LRAD8388
LRAD4241
LRAD0664
LRAC1992
LRAB8739

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Sigma-Aldrich

67692

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EPA 502/524.2 VOC Mix 200 μg/mL each component in methanol, analytical standard

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EPA 502/524.2 VOC Mix

The challenge of research and extension to define and implement alternatives to methyl bromide
Noling.W.J and Becker.OJ
Journal of Nematology, 26, 573-573 (1994)
Handbook of Chemicals and Safety (2016)
Fortune Ezemobi et al.
Acta crystallographica. Section E, Structure reports online, 70(Pt 12), 456-461 (2015-01-02)
The title compounds, C9H7NO3, (1), C10H7NO5, (2), and C14H9NO5, (3), are three potentially anti-convulsant compounds. Compounds (1) and (2) are isoindoline derivatives and (3) is an iso-quinoline derivative. Compounds (2) and (3) crystallize with two independent mol-ecules (A and B)
Yulong Xu et al.
The Journal of chemical physics, 137(18), 184501-184501 (2012-11-21)
The bimolecular nucleophilic substitution (S(N)2) reaction of CH(3)Br and OH(-) in aqueous solution was investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology. Reactant complex, transition state, and product complex are identified and characterized in aqueous solution. The potentials
Guy J Hallman et al.
Journal of economic entomology, 104(1), 63-68 (2011-03-17)
Methyl bromide fumigation is widely used as a phytosanitary treatment. Mexican fruit fly, Anastrepha ludens (Loew) (Diptera: Tephritidae), is a quarantine pest of several fruit, including citrus (Citrus spp.), exported from Texas, Mexico, and Central America. Recently, live larvae have
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