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M5026

Sigma-Aldrich

Methyl 4-O-β-D-galactopyranosyl-β-D-glucopyranoside

Synonym(s):

β-D-Gal-[1→4]-β-D-Glc-1→OMe, Methyl β-lactoside

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About This Item

Empirical Formula (Hill Notation):
C13H24O11
CAS Number:
7216-69-5
Molecular Weight:
356.32
MDL number:
MFCD00079443
UNSPSC Code:
12352201
PubChem Substance ID:
24896968

form

solid

storage temp.

−20°C

SMILES string

[H][C@]1(O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O)O[C@H]2[C@H](O)[C@@H](O)[C@H](OC)O[C@@H]2CO

InChI

1S/C13H24O11/c1-21-12-10(20)8(18)11(5(3-15)23-12)24-13-9(19)7(17)6(16)4(2-14)22-13/h4-20H,2-3H2,1H3/t4-,5-,6+,7+,8-,9-,10-,11-,12-,13+/m1/s1

InChI key

FHNIYFZSHCGBPP-ABBMIVAOSA-N

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Lot/Batch Number
077F5026

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K Bock et al.
Carbohydrate research, 202, 131-149 (1990-07-15)
The 2'-,4'-, and 6'-deoxy derivatives of methyl beta-lactoside have been synthesised by deoxygenation at positions 2', 4', and 6', and the 3'-deoxy derivative was obtained by a glycosylation reaction. The 2'-O-methyl, 2'-O-benzyl, 2'-amino-2'-deoxy, and 1'-deuterio derivatives have been synthesized also.
P Fernández et al.
Carbohydrate research, 248, 15-36 (1993-10-04)
The solution conformations of all the possible monomethyl ethers of methyl beta-lactoside have been analysed using molecular mechanics and dynamics calculations and nuclear magnetic resonance data (variable temperature and NOE experiments). The overall shape of all the compounds studied is
D Solís et al.
European journal of biochemistry, 214(3), 677-683 (1993-06-15)
The binding of O-methyl and fluorodeoxy derivatives of methyl beta-lactoside to the Ricinus communis toxin (RCA60) and agglutinin (RCA120) was studied in order to determine the donor/acceptor relationships of the hydrogen bonds between the hydroxyl groups of methyl beta-lactoside and
Xiaosong Hu et al.
Acta crystallographica. Section C, Crystal structure communications, 66(Pt 2), o67-o70 (2010-02-04)
Methyl beta-D-galactopyranosyl-(1-->4)-alpha-D-mannopyranoside methanol 0.375-solvate, C(13)H(24)O(11).0.375CH(3)OH, (I), was crystallized from a methanol-ethanol solvent system in a glycosidic linkage conformation, with varphi' (O5(Gal)-C1(Gal)-O1(Gal)-C4(Man)) = -68.2 (3) degrees and psi' (C1(Gal)-O1(Gal)-C4(Man)-C5(Man)) = -123.9 (2) degrees , where the ring is defined by atoms
P Fernández et al.
Carbohydrate research, 256(2), 223-244 (1994-04-01)
Syntheses of the 3-aminodeoxy (4), 3-deoxy-3-methyl (5), and 3-epi (6) derivatives of methyl beta-lactoside (1) have been achieved from 1 in a straightforward way, and their solution conformations in water and dimethyl sulfoxide analysed through molecular mechanics and dynamics calculations
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