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716715

Sigma-Aldrich

(S)-2-[(Diphenylphosphino)methyl]pyrrolidine

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250 MG
CHF 91.20

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250 MG
CHF 91.20

About This Item

Empirical Formula (Hill Notation):
C17H20NP
CAS Number:
Molecular Weight:
269.32
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

CHF 91.20


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form

liquid

optical activity

[α]22/D −24.0°, c = 0.5 in ethanol

refractive index

n20/D 1.614

density

1.043 g/mL at 25 °C

functional group

phosphine

SMILES string

C1CN[C@@H](C1)CP(c2ccccc2)c3ccccc3

InChI

1S/C17H20NP/c1-3-9-16(10-4-1)19(14-15-8-7-13-18-15)17-11-5-2-6-12-17/h1-6,9-12,15,18H,7-8,13-14H2/t15-/m0/s1

InChI key

IWRBGJKCDORZHK-HNNXBMFYSA-N

Application

Catalytic ligand in:
  • Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans
  • Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

>230.0 °F - closed cup

Flash Point(C)

> 110 °C - closed cup


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