Skip to Content
Merck
All Photos(2)

Documents

710199

Sigma-Aldrich

Lithium ammonia borane

greener alternative

technical grade

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
LiNH2 ⋅ BH3
CAS Number:
99144-67-9
Molecular Weight:
36.80
UNSPSC Code:
26111700
PubChem Substance ID:
329762906
NACRES:
NA.23

grade

technical grade

form

solid

greener alternative category

Enabling

storage temp.

2-8°C

SMILES string

[Li+].B.[NH2-]

InChI

1S/BH3.Li.H2N/h1H3;;1H2/q;+1;-1

InChI key

DXMCHLDQUBTYRZ-UHFFFAOYSA-N

Application

Lithium ammonia borane (LiNH2BH3) is an alkali-metal amidoborane that is mainly used in hydrogen storage applications. It has a hydrogen release percentage of ~10.9% at a low temperature (~90°C).

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H260,H314

Hazard Classifications

Skin Corr. 1B - Water-react 1

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 1

1 of 1

Borane tetrahydrofuran complex solution 1.0 M in THF

Sigma-Aldrich

176192

Borane tetrahydrofuran complex solution

High-capacity hydrogen storage in lithium and sodium amidoboranes
Xiong Z, et al.
Testing, 7(2), 138-141 (2008)
Myers, A. G.; Yang, B. H.; Kopecky, D. J.
Tetrahedron Letters, 37, 3623-3623 (1996)
Rules and trends of metal cation driven hydride-transfer mechanisms in metal amidoboranes
Kim DY, et al.
Physical Chemistry Chemical Physics, 12(20), 5446-5453 (2010)
Hydrogen-Release Mechanisms in Lithium Amidoboranes
Kim DY, et al.
Chemistry?A European Journal , 15(22), 5598-5604 (2009)
Zhitao Xiong et al.
Nature materials, 7(2), 138-141 (2007-12-25)
The safe and efficient storage of hydrogen is widely recognized as one of the key technological challenges in the transition towards a hydrogen-based energy economy. Whereas hydrogen for transportation applications is currently stored using cryogenics or high pressure, there is

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service