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698709

Sigma-Aldrich

Allylboronic acid MIDA ester

Synonym(s):

2-Allyl-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

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About This Item

Empirical Formula (Hill Notation):
C8H12BNO4
Molecular Weight:
197.00
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:

form

solid

SMILES string

CN1CC(=O)OB(CC=C)OC(=O)C1

InChI

1S/C8H12BNO4/c1-3-4-9-13-7(11)5-10(2)6-8(12)14-9/h3H,1,4-6H2,2H3

InChI key

RKMASTMFHKLQNL-UHFFFAOYSA-N

Other Notes

May contain up to 10 wt. % dimethyl sulfoxide.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Sabin Llona-Minguez et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(20), 7394-7398 (2015-03-27)
A two-step synthesis of structurally diverse pyrrole-containing bicyclic systems is reported. ortho-Nitro-haloarenes coupled with vinylic N-methyliminodiacetic acid (MIDA) boronates generate ortho-vinyl-nitroarenes, which undergo a "metal-free" nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide

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