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About This Item
Empirical Formula (Hill Notation):
C5H4IN
CAS Number:
Molecular Weight:
205.00
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
mp
53-56 °C (lit.)
SMILES string
Ic1cccnc1
InChI
1S/C5H4IN/c6-5-2-1-3-7-4-5/h1-4H
InChI key
XDELKSRGBLWMBA-UHFFFAOYSA-N
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General description
3-Iodopyridine is a heteroaryl halide. It undergoes microwave-assisted coupling with heterocyclic compounds (pyrazole, imidazole, pyrrole and indole) to afford the corresponding N-3-pyridinyl-substituted heterocyclic compounds.
Application
3-Iodopyridine may be used to synthesize following pyridine alkaloids:
- theonelladins C
- theonelladins D
- niphatesine C
- xestamine D
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
224.1 °F - closed cup
Flash Point(C)
106.7 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Alina K Feldman et al.
Organic letters, 6(22), 3897-3899 (2004-10-22)
[reaction: see text] 1,4-Disubstituted 1,2,3-triazoles are obtained in excellent yields by a convenient one-pot procedure from a variety of readily available aromatic and aliphatic halides without isolation of potentially unstable organic azide intermediates.
Microwave-assisted solvent-and ligand-free copper-catalysed cross-coupling between halopyridines and nitrogen nucleophiles.
Ernst, R. F.
Green Chemistry, 13(1), 42-45 (2011)
Synthesis of pyridine alkaloids via Pd-catalyzed coupling of 3-iodopyridine, 1, ?-dienes and nitrogen nucleophiles.
Larock RC and Wang Y.
Tetrahedron Letters, 43(1), 21-23 (2002)
Cameron C Bright et al.
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Small nitrogen containing heteroaromatics are fundamental building blocks for many biological molecules, including the DNA nucleotides. Pyridine, as a prototypical N-heteroaromatic, has been implicated in the chemical evolution of many extraterrestrial environments, including the atmosphere of Titan. This paper reports
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