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516147

Sigma-Aldrich

6-Methyl-2,2′-dipyridyl

97%

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About This Item

Empirical Formula (Hill Notation):
C11H10N2
CAS Number:
56100-22-2
Molecular Weight:
170.21
MDL number:
MFCD02093688
UNSPSC Code:
12352100
PubChem Substance ID:
24873868
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.607 (lit.)

bp

117-119 °C/0.1 mmHg (lit.)

density

1.09 g/mL at 25 °C (lit.)

SMILES string

Cc1cccc(n1)-c2ccccn2

InChI

1S/C11H10N2/c1-9-5-4-7-11(13-9)10-6-2-3-8-12-10/h2-8H,1H3

InChI key

LLCYXFYLGPOKQO-UHFFFAOYSA-N

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BGBC2895V
BGBC1416V
1396131
1441106
03507MD

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Efficient synthesis of 4-, 5-, and 6-methyl-2, 2'-bipyridine by a Negishi cross-coupling strategy followed by high-yield conversion to bromo-and chloromethyl-2, 2'-bipyridines.
Savage SA, et al.
The Journal of Organic Chemistry, 63(26), 10048-10051 (1998)
Bobo Skillinghaug et al.
The Journal of organic chemistry, 79(24), 12018-12032 (2014-10-09)
A fast and efficient protocol for the palladium(II)-catalyzed production of aryl ketones from sodium arylsulfinates and various organic nitriles under controlled microwave irradiation has been developed. The wide scope of the reaction has been demonstrated by combining 14 sodium arylsulfinates
Chemical Constitution and Activity of Bipyridylium Herbicides. XII. Diquaternary Salts of 6-Methyl-2, 2'-bipyridyl and 2-Methyl-4, 4'-bipyridyl.
Schmalzl K and Summers L.
Australian Journal of Chemistry, 30(3), 657-662 (1977)
Synthesis, spectroscopy, and electrochemistry of ruthenium (II) complexes of 6-(N-pyrazolyl)-and 6-(N-pyrazolylmethyl)-2, 2'-bipyridines: new tridentate ligands.
Downard AJ, et al.
Inorganic Chemistry, 30(91), 3733-3737 (1991)

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